一种金微环电极的制作.pdfVIP

一种金微环电极的制作 吴锁柱，苏彬* 浙江大学化学系微分析系统研究所 杭州 310058 电话：座机电话号码 ；Email 地址：subin@zju.edu.cn 微环电极是一种常见的微电极，具有常规电极无法比拟的优点如较快的传质 速率、较小的iR 降等[1]。自从它被提出以来，就引起了研究者的广泛关注[2]。 目前，常见的金属微环电极主要采用真空喷镀的方法制得[1, 3]，但这种方法需 要特殊的仪器设备来满足高度真空的条件，从而在一定程度上限制了其应用。本 文提出了一种采用化学镀技术在聚碳酸酯棒基底上制备金微环电极的方法。首 先，将聚碳酸酯棒在紫外灯下曝光，棒表面就会产生羧基；然后将其浸于银氨溶 液中形成化学镀金所需的银催化中心；最后将棒置于镀金液中镀金，镀好金的聚 碳酸酯棒末端连接铜贴进行导电，用胶密封即可制成金微环电极。用二茂铁甲醇 对制备的电极进行了初步表征，获得了S 型的循环伏安响应曲线。该电极制作方 法具有工艺简单、成本低、易于普及使用等优点。 图-1. 金微环电极在1 mM 二茂铁甲醇 0.1 M 硝酸钾 中的循环伏安图, 扫速1 mV/s. 致谢: 感谢国家自然科学青年基金和浙江大学特聘研究员科研启动经费的支持。 参考文献： [1] C.G. Zoski, Electroanalysis 14 2002 1041-1051. [2] B.A. Brookes, D.J. Gavaghan, R.G. Compton, Journal of Physical Chemistry B 106 2002 4886-4896. [3] D.R. Macfarlane, D.K.Y. Wong, Journal of Electroanalytical Chemistry 185 1985 197-202. A method for the fabrication of gold microring electrode Suozhu Wu, Bin Su* Institute of Microanalytical Systems, Department of Chemistry, Zhejiang University, Hangzhou 310058, China Phone: 座机电话号码; Email address: subin@zju.edu.cn. Microring electrode, as one kind of microelectrodes, has the advantages such as rapid mass transfer rate and low iR drop when compared with the conventional electrode [1]. Since the introduction of this type of microelectrode, it has been focused by many researchers [2]. Recently, the commonly used method for fabrication the metal microring electrode is by vacuum sputtering technique [1, 3]. However, this method requires special equipment to meet the high vacuum conditions, which limits its wide applications. This work presents a chemical plating technique for fabrication the gold microring electrode on a polycarbonate rod. First, the polycarbonate rod was exposed in the UV light to produce carboxyl groups on its surface. Then, the rod was immersed in an Ag NH + solution to form the silver catalytic center. Finally, the rod 3 2 was placed in the gold plating solution for the gold deposition on the surface of t