锂离子电池隔膜性能的对比研究.pdfVIP

第30届全国化学与物理电源学术年会 锂离子电池隔膜性能的对比研究 ＊ 潘笑容，连芳 ，关红艳，何逸，文焱 （北京科技大学材料科学与工程学院北京 100083） 摘要：本文对锂离子电池用 PP 膜、Al O 改性后的 PP 膜、静电纺 PVDF-HFP 复合 PP 膜和 PP/PE/PP 三层膜进行 2 3 了物理性能和电化学性能的对比研究。吸液率测试结果表明，经过 Al2O3 和 PVDF-HFP 表面改性后，PP 膜的吸 液率分别由 110%上升到 150%、217%，与电解液的亲和性有所提高。使用不同隔膜分别组装 Li/LiMn2O4 半电池， 其交流阻抗和恒流充放电测试表明，PP/PE/PP 三层膜组装的电池循环性能良好，溶液阻抗最低，放电比容量最 高为 99.7 mAh/g ；与未改性的 PP 膜相比，经过 Al2O3 改性的 PP 膜组装的电池溶液阻抗更低，放电比容量更高， 而经过 PVDF-HFP 表面改性的 PP 膜组装的电池溶液阻抗降低，放电比容量未发生明显变化。 关键词：锂离子电池；隔膜；吸液率；电化学性能 Comparative research on properties of different separators for lithium ion batteries ＊ Xiao-rong Pan, Fang Lian , Hong-yan Guan, Yi He , Yan Wen (School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083) Abstract ：The physical and electrochemical properties of polypropylene (PP) membrane ，PP membrane modified with Al O ，PP membrane electrospun with PVDF-HFP and PP/PE/PP trilamellar membrane have been studied. The results 2 3 of liquid electrolyte uptake test show that, after modified with Al2O3 and electrospun with PVDF-HFP, the affinity with liquid electrolyte is improved, and the liquid electrolyte uptakes of PP membranes are increased from 110% to 150%, 217% respectively. In addition, AC impedance test and the galvanostatic charge/discharge test show that Li/LiMn2O4 cell assembled with PP/PE/PP trilamellar membrane has good cycling performance, the lowest solution impedance and the highest discharge specific capacity of 99.7 mAh/g. Compared with PP membrane, the battery assembled with Al2O3 modified membrane has lower solution impedance and hi