三苯胺偶氮化合物的MALDI_TOF质谱研究_王振鹏.pdfVIP

28 1 Vol. 28　No. 1 2007 2 Journal of Chinese Mass S ectrometry Society Feb. 2007 MALD-I TOF 王振鹏,赵镇文,辛　斌,胡伟华, 熊少祥 (, 　100080) :。、, 、、。: , , , 。 :(MALD-I T OF MS); :O657. 63;R917 　　:A 　　:100-4 2997(2007)0-1 27-04 Analysis of Triphenylamine Azo Compounds by MALDI-TOF MS WANG Zhen-eng, ZHAO Zhen-wen, XIN Bin, HU We-i hua, XIONG Shao-xiang (B eij ing Mass Sp ectrom etry Cen ter, I ns titute of Chem istry , Ch inese A cademy of S ciences, B eij ing 100080, China) Abstract:The tri henylamine azo com ounds w ere successfully characterized by matrix-as- sisted laser desor tion-ionization time of flight mass s ectrometry (MALD-I TOF M S). The influence of matrix, ion detection mode and concetration of sam le w as investigated in de- tail. The satisfactory mass s ectra can be obtained using norharmane as matrix under nega- tive ion detection mode. Key words:MALD-I TOF M S;tri henylamine azo com ounds 　　(MALDI) 80 er ;, 337 nm; “”, (delayed extraction) [1] 、 , (reflectron),、 、, 。 [2-4] 。 MA LDI-TOF -α-4- MS ,(EI) (CCA ), 2, 5-(DHB), (nH), , (DI), 3-(3-AQ ) MA LD-I TOF M S Sigma ; ,、、, , 。 1。 . 2　 　 1 g - 1 . 　 L 。CCA 、DHB、nH 、3-AQ 、DI BIFLEX Ⅲ MA LDI-TOF :Bruk- 20 g L- 1 , A gAc、NaCl :2006-0-3 14;:200-6 0-9 01 :(1982 ～), (), , , 。 :(1956 ～), (), , , 、。E-mail:m scbj @iccas. ac. cn 28 　　　　　　　　　　　　　　　　　 28 　 。3 μL , 1μL , ,。1 0. 5 μL , 1A,