熔融旋甩制备Ce0.8Fe4-xNixSb12方钴矿热电性能研究.pdfVIP

G6 熔融旋甩制备 Ce Fe Ni Sb 方钴矿的热电性能研究 0.8 4-x x 12 谭刚健 鄢永高 李涵 苏贤礼 唐新峰﹡ （武汉理工大学材料复合新技术国家重点实验室，湖北武汉 430070） 摘要：采用熔融旋甩（MS）技术结合放电等离子烧结（SPS）工艺制备了方钴矿化合物Ce Fe Ni Sb (x=0~0.15)， 0.8 4-x x 12 并对样品进行了相组成及微观结构分析和热电性能表征。研究结果表明，所有样品均为单相且呈P型传导。Ni 对 Fe 进行取代后，电导率有一定程度下降，但 Seebeck 系数得到显著提高。然而由于 Ni 取代同时导致了载流子热 导的降低以及合金化散射引起晶格热导率减小而使其总热导率大幅度下降。其中，x=0.05和x=0.10样品在800K 时最大无量纲热电优值均达到0.73，相比于参比样Ce Fe Sb 提高了约18%。 0.8 4 12 关键词：熔融旋甩；方钴矿；热导率；热电性能 Thermoelectric properties of Ce Fe Ni Sb compounds 0.8 4-x x 12 prepared by MS+SPS technique TAN Gangjian, YAN Yonggao, LI Han, SU Xianli, TANG Xinfeng ﹡ (State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan university of technology, Wuhan, 430070, China) Abstract: Single-phase skutterudite compounds with highly relative density Ce Fe Ni Sb (x=0~0.15) 0.8 4-x x 12 were prepared by combining melt spinning technique with spark plasma sintering. Their phase structure, microstructure and thermoelectric properties were investigated. The result reveals that all samples show p-type conduction. When Fe was substituted by Ni, the electrical properties can be reduced to some extent, but the total thermal conductivity is decreased more evidently due to the reduction of 　c caused by decreased carrier concentration and 　 L caus