两亲性聚合物复合微球的制备和性能研究.pdfVIP

两亲性聚合物复合微球的制备及性能研究 杨穆 郭阳光 王戈 北京科技大学材料科学与工程学院，北京，100083 两亲性颗粒因其表面具有不同的物理化学性质，在表面活性剂、催化、自组装、传感器、 生物医药等领域具有广阔的应用前景[1-5]。本研究采用多步种子溶胀聚合法，通过调控相分离 过程中的热力学和动力学因素，制备出了爆米花形、雪人形等两亲性聚合物复合微球。首先 对具有一定交联结构的PS微球表面进行改性处理，得到表面为亲水性的磺酸聚苯乙烯、内 部为PS的核壳型结构颗粒，再次溶胀聚合使微球内核粒径增大，并发生初步相分离，之后 进一步溶胀聚合使相分离更加明显，从亲水表面相分离形成新的PS油相，得到爆米花形颗 粒(Fig.(1)b)。 Thesynthesisandpropertiesoftheamphiphilicpolymercomposite microspheres YANG Mu WANGGe GUOYangguang SchoolofMaterialsScienceandEngineering,UniversityofScienceandTechnologyBeijing, Beijing,100083 Abstract:Amphiphilicparticleshavetheasymmetricsurfacephysicalandchemicalproperties. Suchauniquestructuremakesthemsuitableforapplicationsinmanyareas,suchassurfactant, catalysis,self-assembly,optics,sensors,biomedicalmedicine[1-5].Inthisstudy,wesynthesize amiphiphilicpolymerparticlebycombiningthemodifiedtreatmentandmultistageseedswelling polymerization.Thecore-shellPSparticlesweregainedbymodifyingthecross-linkedPSparticles withconcentratedsulfuricacid,andthesurfaceoftheparticleswashydrophilic.Withtwiceseeded swellingpolymerization,thehydrophilicsurfaceappearsanewPSoilphase,resultingtothe formationofamphiphilicpopcorn-likepolymercompositemicrospheres.Adjustingthecrosslinking degreeofseedmicrospheres,theswellingratioandtheamountofswellingagent,amphiphilic polymercompositemicrosphereswithdifferentmorphologiesareobtained. Keywords: Seedswellingpolymerization ; Phaseseparation ; Hydrophilic ; Lipophilic