NaCl与分散剂对相变储能蜡微胶囊制备的影响.pdfVIP

Vol37 No1 37 1 56 NEW CHEM ICAL MATERIALS 2009 1 NaCl 鄢 瑛 刘 剑 张会平 (华南理工大学化学与化工学院, 广州510640) 以常低温相变储能蜡RT 31 为芯材,脲 树脂为壁材, 采用原位聚合法制备了相变储能蜡微胶囊利用傅 立叶红外光谱仪扫描电子显微镜差示扫描量热仪等对样品进行分析和表征, 讨论了助剂NaCl 及两种不同类型的分散 剂对微胶囊性能和形貌的影响实验结果表明, 加入 一定量的NaCl 能显著提高微胶囊的相变潜热, 使得微胶囊的包封率 由758%升高到925%,在微胶囊成型后期加入 一定量的分散剂能明显改善微胶囊的表面形貌和粒径均匀度 石蜡, 相变材料, 微胶囊相变材料, NaCl,分散剂 Ef fects of NaCl and dispersants on preparation of microencapsulated phase change paraffin an ing Liu Jian Zhang Huiping ( School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640) Abstract Microencapsulated phase change paraffin was prepared by insitu polymerization with ureaformaldehyde resin as shell and phase change paraffin RT31 as core. T he properties of the products were analyzed and characterized by FTIR, SEM and DSC. The effects of the NaCl and two different kinds of dispersants on the properties and morphologies of the microcapsules were investigated. Experimental results showed that latent heat of microcapsules was improved greatly by adding NaCl, which made microcapsules encapsulation efficiency increased from 758% to 925%,the morphologies and uniformity of particles diameter of microcapsules were improved clearly by adding dispersants in the latter part of forming microcapsules. Key words paraffin, phase change material, microencapsulated phase change material, NaCl, dispersant , 1 ,, , , , 1. 1 RT31, RUBITHERM ; 6060 [ 1]