辛癸酸甘油酯气相色谱质谱分析.pdfVIP

第六期 香料香精化妆品 No. 6 二o o 二年十二月 FLAVOUR FRAGRANCE CO MET IC December, 2002 P ( , 310027) Determination of the Composition of ODO by Gas Chromatograph- EI Mass pectrometry Zou Jiankai (Department of Chemistry, chool of cience, Zhejiang University, Hangzhou 310027) Abstract A Gas chromatograph- EI Mass spectrometry method was developed for analyzing the composition of ODO with HP 5M 30m @ 0. 25mm @ 0. 25Lm capillary column. T he main glycerol esters among ODO sample were tricaprylin, dioctyl decoylglyce- rol and octyl didecoylglycerol. Key words: P, HP- 5M 30m @ 0. 25mm @ 0. 25Lm , , , , , , EI : P P 1 [ 1, 2] P, ( ODO) , ( GCPM ) , ( ODO) , 2 , 2. 1 仪器 HP6890P5973 ( GC PM ) , HP- (HPLC) ( GC) 5M 30m @ 0. 25mm @ 0. 25Lm , P 1 GCPM (T IC) : 2002- 03- 20 ) 16 ) 香料香精化妆品 二o o 二年十二月 , 250l , N I T 10 N T 2. 2 分析条件 , 7 127( C7H 15CO) , 327( M - 320 e , 320 e , M- C7H15COO) , 10 155( C9H 19CO) , 383 240 e ( 2min) 20 e Pmin 340 e ( 3min) ( M- C9H19COO) , , 1ml Pmin, 250 e , , RCO M - RCOO 190 e , 70eV, 1. , 5kV, 30~ 600amu, 3min 9 : 127 ( C7H 15CO ) , 155 100B1, 1Ll