网化聚氨酯泡沫塑料的制备、微观结构及储油性能.pdfVIP

114 2013年中国工程塑料复合材料技术研讨会论文集 网化聚氨酯泡沫塑料的制备、微观结构及其储油性能 潘恒太，张广成，范晓龙，赵龙 (西北工业大学理学院应用化学系，西安710129) 摘要：以聚醚多元醇330N和甲苯二异氰酸酯为主要原材料，三乙醇胺和二月桂酸二丁基锡为催化剂，蒸馏水和 三氟三氯乙烷为发泡剂，并加入匀泡剂和开孔剂制备软质开孔聚氨酯泡沫塑料，通过碱液水解法制备网化聚氨酯泡 沫塑料。采用光学显微镜及扫描电子显微镜观察泡沫塑料泡孔的微观结构，采用吸油速率和吸油率以及排油速率和 油残存率表征网化聚氨酯泡沫塑料的储油能力。结果表明，通过调节两种催化剂用量可以有效控制泡沫塑料的凝胶 速率和发泡速率，通过调节两种发泡剂用量可以有效控制泡沫塑料的密度及平均泡孔尺寸，通过调节匀泡剂和开孔 剂用量可以有效控制泡沫塑料的孔径、孔径分布及开孔率。碱液浸泡时间为5min时，泡沫塑料的泡壁基本被完全除 净，而泡棱保留较为完整，拉伸性能无明显下降。制备出的网化聚氨酯泡沫塑料具有良好的吸油及排油性能，有望作 为油箱填充材料使用。 关键词：网化聚氨酯泡沫；制备；泡孔结构；储油性能 andOil BehaviorsofReticulated FoamPlastics Preparation，MicrostructureAbsorption Polyurethane Pan Hengtai，ZhangGuangcheng，FanXiaolong，ZhaoLong ofScience，NorthwestemUniversity，Xi’an710129，China) (DepartmentofAppliedChemistry，School Polytechnical the andtoluene asbasicraw and dilaurate Abstract：Takingpolyetherpolyol diisocyanate materials，triethanolaminedibutyltin as waterandtrifluorotrichloroethaneas foamstabilizerandcell cellflexible catalysts，distilled foamingagents，adding opener,open foam were reticulated foam were alkaline prepared hydrolysis polyurethaneplasticsprepared．Thenpolyurethaneplastics through method．Themicrostructuresoffoam werecharacterized and electron oil by microscope microscope，the plastics optical scanning rateand ratio．Theresultsindicates abilitieswerecharacterizedoil residual storage by absorptionrate，absorptionratio，dischargi