新的前驱物热解制备纳米镍氧化物.pdfVIP

Journal of Alloys and Compounds 493 (2010) 163–168 Contents lists available at ScienceDirect Journal of Alloys and Compounds j o u rn al h omepage: w w w. elsev /locate/jallcom A novel precursor in preparation and characterization of nickel oxide nanoparticles via thermal decomposition approach Masoud Salavati-Niasari a,b,∗ , Noshin Mir b , Fatemeh Davar a a Institute of Nano Science and Nano Technology, University of Kashan, Kashan, P.O. Box 87317-51167, Islamic Republic of Iran b Department of Inorganic Chemistry, Faculty of Chemistry, University of Kashan, Kashan, P.O. Box. 87317-51167, Islamic Republic of Iran a r t i c l e i n f o a b s t r a c t Article history: In order to raise the need of co-surfactant in the synthesis of NiO nanoparticles, [bis(2-hydroxy-1- Received 24 August 2009 naphthaldehydato)nickel(II)] complex was employed as a novel precursor in thermal decomposition Received in revised form process using oleylamine (C18H37 N) as surfactant. The products were characterized by X-ray diffraction 22 November 2009 (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform Accepted 23 November 2009 Available online 26 November 2009 infrared (FT-IR) spectroscopy, thermogravimetric analysis (TGA), X-ray photoelectron spectroscopy (XPS) and ultraviolet–visible (UV–Vis) spectroscopy. Also the novel precursor thermally was treated in solid state react