染料敏化可见光催化制氢研究进展.pdfVIP

物理化学学报(Wuli Huaxue Xuebao) 612 Acta Phys. -Chim. Sin. 2015, 31 (4), 612-626 April [Review] doi: 10.3866/PKU.WHXB201502041 染料敏化可见光催化制氢研究进展 刘 兴1,2 李越湘1,* 彭绍琴1 赖 华2 1 2 ( 南昌大学化学系, 南昌330031; 衡阳师范学院化学与材料科学系, 湖南衡阳421008) 摘要: 染料敏化是拓展宽禁带光催化剂激发波长范围、有效利用太阳光中可见光部分的重要手段. 本文介绍 了染料敏化分解水制氢的基本原理, 综述了染料敏化剂、基质或载体、染料与基质的相互作用、产氢助催化剂以 及电子牺牲剂的研究进展. 并对光敏化体系中电荷转移途径及稳定性问题进行了讨论. 关键词: 光催化制氢; 染料敏化; 敏化剂; 敏化基质; 稳定性 中图分类号: O643 Progress in Visible-Light Photocatalytic Hydrogen Production by Dye Sensitization LIU Xing1,2 LI Yue-Xiang1,* PENG Shao-Qin1 LAI Hua2 1 ( Department of Chemistry, Nanchang University, Nanchang 330031, P. R. China; 2Department of Chemistry and Material Science, Hengyang Normal University, Hengyang 421008, Hunan Province, P. R. China) Abstract: Dye sensitization is an important strategy for broadening the excitation wavelength range of wide- band-gap photocatalysts to use visible light from the sun. In this paper, the primary principle of dye-sensitized water splitting for hydrogen production was introduced, and the research progress in dye sensitizers, sensitized matrixes or supporters, the interaction between dyes and matrixes, co-catalysts for hydrogen evolution, and sacrificial electron donors were all reviewed. Moreover, the pathways of charge transmission and stability issues in dye-sensitized systems were discussed. Key Words: Photocatalytic hydrogen production; Dye sensitization; Sensitizer; Se