土壤富里酸对铅的吸附作用和影响因素研究.pdfVIP

2009 年 10 月 第三届全国农业环境科学学术研讨会论文集 405 ∗ 土壤富里酸对铅的吸附作用与影响因素的研究 1 2 翟莹雪 ，魏世强 （1.西南大学地理科学学院，重庆北碚 400715；2.西南大学资源与环境学院，重庆北碚 400715） 摘 要：本论文采用改进的连续电位滴定法，研究了土壤富里酸对重金属铅吸附量的主要影响因素。通过调节富里 酸溶液的 pH 值、富里酸浓度、温度和离子强度，得到吸附量的变化情况，结论如下：溶液 pH 从 10.0 滴定至 2.5， 富里酸对铅的吸附量降低，pH 对吸附量的影响可用自然对数方程进行拟合，通过各处理中自然对数方程的比较得出， 富里酸浓度越小、金属离子浓度越大，方程的斜率越大，说明吸附量的大小同时与二者密切相关；溶液中富里酸浓 度升高，相应的吸附量降低，但吸附率升高；温度升高，吸附量增加；离子强度在设定的范围内，从 0.1 mol·L-1 加 至 0.5 mol·L-1 ，吸附量逐步降低。 关键词：富里酸，铅，电位滴定，吸附 Influencing Factors and Lead Adsorption by Soil Fulvic Acid 1 2 ZHAI Ying-xue , WEI Shi-qiang (1.School of Geographical Sciences, Southwest University, Chongqing 400715, China；2.School of Resources and Environment, Southwest university, Chongqing 400715, China) Abstract: In soil, FA(fulvic acid) can control the lead ions’ biologic validity, which can be influenced by several soil conditions such as FA concentration, pH, temperature and ion strength in FA-Lead solution and so on. In this study the modified potentiometrictitration was used. We changed the pH, the concentration of FA, the temperature and the ion strength in FA-Lead solution and found that this four matters above can all affect the interaction of FA with Lead ions. By titrating the FA-Lead solution, the conclusion could be drawn as follows: the amount of lead ions absorbed by per gram of fulvic acid grew with the increasing of pH from 2.5 to 10.0, which could be simulated by the natural logistic equation. The higer concentration of FA and the lower concentration of Lead ions, the lower slope of the equation was, which proved that the amount of Lead ions absorbed by per gram of fulvic aci