某些有机添加剂对硫酸酒石酸盐溶液中电沉积CuZn合金的作用.pdf

【研究报告】 Actions of certain organic additives on Cu-zn alloy electrodeposition from sulfate-tartrate solutions K Amutha ， K R Marikkannu ， P ShakkthivaI ， T Vasudevan ， G ParuthimaI KaIaignan （Dept. of IndustriaI Chemistry ，AIagappa University ，Karaikudi 630003 ，India ） Abstract ：Cu-zn coatings obtained by eIectrodeposition 剂，而硫脲、甘油是阻化剂。采用动电位极化和电化学阻抗谱 方法，测定了Cu-zn 合金镀层在NaCI （ = 3. 5% ）溶液中的耐 from acidic suIphate soIutions containing sodium potassium ! tartrate and trisodium citrate as the compIexing agents have 蚀性能。采用扫描电镜研究了添加剂对控制沉积质量的微妙 been studied. The effects of current density ，pH and tem- 作用。X - 射线衍射分析表明，合金镀层的相结构是正交晶。 在上述研究的基础上，提出了Cu-zn 合金电沉积的最佳组成 perature on the throwing power of the bath as weII as their 和工艺控制参数。 effect on the aIIoy composition were evaIuated. The soIution 关键词：铜锌合金；电沉积；有机添加剂；硫酸- 酒石酸盐溶 affords good throwing power and current efficiency in pres- 液；耐蚀性能 ence of the additives under the experimentaI conditions. Of 中图分类号： Tol53 文献标识码：A the different additives tried saccharin and phenoI are found 文章编号：l004 - 227X（2006 ）0l - 000l - 06 to be acceIerators whiIe thiourea and gIycerine are retarders on the eIectrodeposition processes. The Cu-zn deposits ob- tained with the