SBA-15负载硅钨酸催化环己酮Baeyer-Villiger氧化.pdf

2011 Chinese Journal of Catalysis Vol. 32 No. 3 文章编号: 0253-9837(2011)03-0463-05 DOI : 10.3724/SP.J.1088.2011.00928 研究论文: 463~467 SBA-15 负载硅钨酸催化环己酮Baeyer-Villiger 氧化 杨志旺, 马振宏, 牛棱渊, 马国富, 马恒昌, 雷自强 西北师范大学化学化工学院, 生态环境相关高分子材料教育部重点实验室, 甘肃省高分子材料重点实验室, 甘肃兰州 730070 摘要：采用浸渍法制备了 H4O40 SiW12/SBA-15 催化剂, 通过红外光谱、X 射线衍射、N2 吸附-脱附和透射电镜等方法对催化剂 进行了表征. 结果表明, H4O40 SiW12 能均匀分散于 SBA-15 的孔道中, 催化剂仍保持载体的介孔结构和硅钨酸的 Keggin 型结 构. 将催化剂用于环己酮的 Baeyer-Villiger 氧化反应中, 考察了催化剂用量、温度和时间等对反应性能的影响. 当催化剂用量 o 为 10 mg, 在 70 C 反应 8 h 时, 环己酮转化率达 86%, 产物内酯选择性可达 99%. 同时, 催化剂具有一定的重复使用性能. 关键词：环己酮; Baeyer-Villiger 氧化反应; 内酯; 硅钨酸; SBA-15 分子筛 中图分类号：O643 文献标识码：A Baeyer-Villiger Oxidation of Cyclohexanone Catalyzed by SBA-15 Supported Silicotungstic Acid * YANG Zhiwang, MA Zhenhong, NIU Lengyuan, MA Guofu, MA Hengchang, LEI Ziqiang Key Laboratory of Eco-Environment-Related Polymer Materials of Ministry of Education, Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, Gansu, China Abstract: Silicotungstic acid (H O SiW ) was supported on SBA-15 with the content of 20% by impregnation. The structure and proper- 4 40 12 ties of the catalyst were characterized by Fourier transform infrared spectroscopy, X-ray diffraction, N2 adsorption-desorption, and transmis- sion electron microscopy. H4O40SiW12 was highly dispe