Controllable One-Pot Synthesis and Enhanced Visible Light Photocatalytic Activity of外文翻译.pdfVIP

940 J. Phys. Chem. C 2010, 114, 940–946 Controllable One-Pot Synthesis and Enhanced Visible Light Photocatalytic Activity of Tunable C-Cl-Codoped TiO2 Nanocrystals with High Surface Area Hua Xu and Lizhi Zhang* Key Laboratory of Pesticide and Chemical Biology of the Ministry of Education, College of Chemistry, Central China Normal UniVersity, Wuhan 430079, People’s Republic of China Recei Ved: October 15, 2009; ReVised Manuscript ReceiVed: NoVember 20, 2009 We demonstrate the controlled synthesis of C-Cl-codoped anatase TiO2 nanocrystals by hydrolysis of titanium tetraisopropoxide (TTIP) in chloroform containing trace amounts of water at a low temperature of 150 °C without subsequent thermal procedure. The C and Cl dopants resulted from the solvothermal decomposition of chloroform induced by water, and the adjusting of molar ratios of water to TTIP was able to tune the crystal sizes and the concentration of the dopants. The as-prepared powders were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), high-resolution TEM (HRTEM), nitrogen adsorption, X-ray photoelectron spectroscopy (XPS), and UV-vis diffuse reflectance spectroscopy (DRS). All the C-Cl-codoped TiO2 possessed mesoporous structure and high surface areas between 158.1 and 469.6 2 m /g. The photocatalytic activities of the resulting C -Cl-codoped TiO2 nanocrystals were evaluated by the photodegradation of RhB under visible light irradiation. The sample synthesized with a molar ratio of water to TTI