红色长余辉料的制备和性能研究.pdfVIP

摘复 摘 要 长余辉的制备和性能越来越受到人们的重视。CaS：Eu‘’-等传统的红色}乏余辉材 或光解，无法满足实际使1E}{要求。本文研究了两种性能稳定的新型红色长余辉蓄 法。研究了两种红色长余辉蓄能材料的光谱、热释光、激活剂和共激活剂对材料 性能的影响。着重研究了Pr3+摩尔浓度对CaTi03：P，+材料，陆能的影响，随着Prp 浓度的增加表现出明显的猝灭现象；激活剂Eu3+和共激活剂M92卞．Ti4+的摩尔浓 陷阱能级的形成，从而明显延长了余辉时涮，M92+的日I入起电茼补偿的作用。用 共沉淀法制备Y202S：Eu计．M92+．Ti4一材料更有利于潋活剂Eu3一均匀掺入基质品 格。 的认识。为该类村料的进一步广泛应用丌辟了道路。 Abstraet Withthe of developmentSrAl204：Eu斗，De+yellow—greenlongafterglow and ofred were more characteristic longafterglow phosphor,thepreparation paid attention．Nottheluminescencecharacteristicofthetraditionalred only long CaS：Eu3‘couldnotbe with phosphor compareSrAl204：Eu2+．Dy”long afterglow ithad inthe ofmoisture also instablecharacteristic phosphor，but exposure afterglow and above limitedits and sunlight．Thedeficiency application．Thepreparation characteristicoftwonewkindsofstablered CaTi03：Pr’+and longafterglowphosphor The methodwas inthe studied sintering Y202S：Eu3+，M92+,Ti“were applied the methodwasusedinthe preparationofphosphors，andco—precipitation preparation ofthe Y203：Eu抖of precwsor spectrum， theeffectofactivatorandco‘activatoronthe themroluminescence curves，and glow