多羧酸和较联吡啶配体构筑的配位聚合物的合成和表征.pdf

II 万方数据 多羧酸和较长联吡啶配体构 筑的配位聚合物的合成和表征 摘要 多羧酸和较长联吡啶配体构筑的配位聚合物的 合成和表征 摘要：由多齿有机配体和金属离子自组装形成的配位聚合物因具有迷人的拓扑结构 并在荧光、催化、吸附、磁性以及非线性光学等方面具有广阔的应用前景而受到了 人们的广泛关注。近年来，多吡啶和多羧酸混合配体经常被人们用来构筑配位聚合 物，而多吡啶配体的长度可以在很大程度上影响产物的结构。然而，在这些体系中， 较长的多吡啶配体却用得不多。最近，我们致力于合成由较长多吡啶和多羧酸架构 的配位聚合物并对它们进行结构的表征。本论文主要选取了两种较长的联吡啶配体 1,4-bis[2-(4-pyridyl)ethenyl]benzene(1,4-bpeb) 和 1,4-bis[2-(4-pyridyl)ethenyl] -2,3,5,6-tetramethylbenzene(1,4-bpetmb) ，用它们分别与多羧酸和金属盐反应，得到 三个配位聚合物 [Cd(μ-H O)(1,4-bpeb)(1,4-pda)]n(1) ， {[Zn(5-NH -1,3-BDC) 2 2 (1,4-bpetmb) 0.5]·2H O}n (2)和[Zn (µ-OH)(1,3,5-BTC)(1,4-bpetmb)]n (3) 。 2 2 关键词：配位聚合物；多羧酸；联吡啶；合成；表征 I 万方数据 多羧酸和较长联吡啶配体构 筑的配位聚合物的合成和表征 Abstract Syntheses and Characterization of Coordination Polymers Constructed by Polycarboxylates and Long Dipyridyl Ligands Abstract ：In recent years, the design and construction of coordination polymers by assembly reactions of multitopic ligands with metal ions have attracted considerable attention. This is due to their intriguing structural topologies and their potentials for use as functional materials in fluorescence, catalysis, adsorption, nonlinear optics and magnetism. In recent years, it is noted that much attention has been paid to the coordination polymers that are assembled by polycarboxylic acids and multipyridyl ligands. The spacer of these m