《Synthesis and Crystal Structure of a Novel Ca（Ⅱ） Coordination Polymer Containing Dipyridine Dicarboxylic Ligand》.pdf

33卷 4期 结 构 化 学 (JIEGOUHUAXUE) Vb1．33．No．4 20l4．4 Chinese J． Struct． Chem． 585—59O SynthesisandCrystalStructureof aNovelCa(II)CoordinationPolymer ContainingDipyridineDicarboxylicLigand~ DarkhijavB SUOQuan--Ling GAOYuan-Y·uan HAIEr-Han XIERui．．Jun ZHU Ning HAN Li．．M in~ (ChemicalEngineeringCollege,lnnerMongoliaUniversityofTechnology,Hohhot010051，China) ABSTRACT ThenovelalkalinemetalcomplexCa(BPDCH)2(1，BPDCH2=2,2-bipyri— dine一5，5-dicarboxylicacid)hasbeensynthesizedbythehydrothermalreactionofCa(NO3)24H20 with2,2-bipyridine一5．5 dicarboxylicacid．Themolecularandcrystalstructuresofcomplex1have firstlybeenchraacterizedbyFTIR,elementalanalysis，andX ·raysingle·crystaldiffraction．The3D MOF structureofcomplex 1was interpretedbytheversatilebindingmodes—theintermolecular hydrogenbondsand7t-Ttstackinginteractionsof2,2-bipyridine一5，5-dicarboxylicacidligand．The analysisresultsshow complex1belongstoacoordinationpolymerwith 3D MOF structure．The resultsofthermogravimetric naalysisand solubility demonstratecomplex 1isathermostable compoundnaddoesnotdissolveinwaterandtraditionalorganicsolvents． Keywords：calcium complex，coordinationpolymer,molecularandcrystalstructure， bipyridine-dicarboxylicligand，thermo-stability 1 INTRoDUCTIoN bechosenasapossiblesubstitutetotheLn metal centerduetocompraablesizesoftheirionicradii During the las[decades，morenadmorezero- (126．6nad126pm for8．coordinatepr3nadCa2， dimensional (OD)，one-dimensional(1D)，two— respectively；131．9 nad 132 pm for9一coordinate