《N,N′-双(2-吡啶甲基)二硫代草酰胺根桥联的三核铜(Ⅱ)配合物的合成及表征》.pdfVIP

无机化学学报990217 无机化学学报 JOURNAL OF INORGANIC CHEMISTRY 1999年 第2期 No.2 1999 N，N′-双(2-吡啶甲基)二硫代草酰胺根桥联的 三核铜(Ⅱ)配合物的合成及表征 崔建中　程　鹏　廖代正　姜宗慧　阎世平　王耕霖 　　关键词：二硫代草酰胺桥联配体　三核铜(Ⅱ)配合物　磁性 　 SYNTHESIS AND CHARACTERIZATION OF TRINUCLEAR COPPER ( Ⅱ) COMPLEXES BRIDGED WITH N,N ′-Bis(2-PYRIDYLMETHYL)- DITHIOOXAMIDATE CUI Jian-Zhong　CHENG Peng　LIAO Dai-Zheng JIANG Zong-Hui　YAN Shi-Ping　WANG Geng-Lin (Department of Chemistry, Nankai University, Tianjin 300071) 　　Two new trinuclear copper( Ⅱ) complexes bridged with N,N ′-Bis(2-pyridylmethyl)- Dithiooxamidate, ［Cu L ］(ClO ) (1) and ［Cu L ］(NO ) (2) (H L=N,N ′-Bis(2- 3 2 4 2 3 2 3 2 2 pyridylmethyl)-Dithiooxamide), have been synthesized, and characterized by elemental analyses, IR, UV-visible spectra, conductance and EPR spectra. The variable temperature magnetic susceptibility for complex (1) has been measured in the range of 1.5～298K. Experimental data of magnetic susceptibility are successfully fit to theoretical value based on the spin Hamiltonian operator: H=-2J(S S +S S )-2J ′S S , S =S =S =1/2, giving the 1 2 2 3 1 3 1 2 3 magnetic exchange parameters of 2J=-170 cm-1 and 2J ′=-7.2 cm-1. This result indicates the presence of a strong antiferromagnetic spin exchange interaction between the Cu( Ⅱ) ions. 　　Keywords:dithiooxamide bridging ligand　trinuclear copper( Ⅱ) complex　 magnetic properties 0　前　言 　　多原子桥联配体的多核配合物中，顺磁离子间磁偶合作用的研究对阐明磁性和结 万方数据 file:///E|/qk/wjhxxb/wjhx99/wjhx9902/990217.htm（第 1／6 页）2010-3-23 10:01:55 无机化学学报990217 构的关系以及设计新型分子基磁性材料具有重要的理论意义。草酸根及草酰胺桥根桥