Si-PhotonicMaterialsGroup.pptVIP

* * * * * * * * * * * * * * * * * * * * * * * * * * * Nanophotonics Class 5 Rare earth and quantum dot emitters H He Li Be B C N O F Ne Na Mg Al Si P S Cl Ar K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn Fr Ra Ac Rf Db Sg Bh Hs Mt Uun Uuu Uub Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr La3+: [Xe] 4f n n=1-14 ….4f n 5s2 5p6 Optical doping with lanthanide ions Energy levels of lanthanide ions 1.5 μm Egap(Si) Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu Europium protects the euro J.F. Suyver, A. Meijerink (UU) Lanthanide bar codes Dejneka, PNAS 100, (2003) ????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? H He Li Be B C N O F Ne Na Mg Al Si P S Cl Ar K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn Fr Ra Ac Rf Db Sg Bh Hs Mt Uun Uuu Uub Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr La3+: [Xe] 4f n n=1-14 ….4f n 5s2 5p6 Optical doping with lanthanide ions Chemistry (outer-shell behavior) is similar A. Polman et al., Appl. Phys. Lett. 62, 507 (1993), J.S. Custer et al., J. Appl. Phys. 75, 2809 (1994) ? Erbium Prasaeodymium Silica optical fiber transmission spectrum 1012 Hz 1.3 ?m 1.55 ?m Miya et al., Electron. Lett. 15, 108 (1979) wavelength vs. time division multiplexing: WDM Erbium transition at 1.5 ?m Er absorption and emission cross sections absorption emission G.N. van den Hoven et al. Appl. Opt. 36, 3338 (1997) ? Erbium photolumi