BaSO4 Catalysts： Effect of Carrier Structure.pdfVIP

Trans．TianjinUniv．2014 20：282—291 DOJ10．1007／sl2209—0142363．Y HydrogenationofCommercialPolystyreneoverPd／BaSO4 Catalysts：EffectofCarrierStructure HanKaiyue(韩凯悦)，MengChen (孟 晨)，ZhuZhenwei(朱振炜)，CaoGuiping(曹贵平) (UNILAB，StateKeyLaboratoryofChemicalEngineering，SchoolofChemicalEngineering，EastChinaUniversityof ScienceandTechnology，Shanghai200237，China) ◎TianjinUniversityandSpringerVerlagBerlinHeidelberg2014 Abstract：Avarietyofbarium sulfate (BaSO4)carrierswithorwithoutmesoporestructureweresynthesizedvia precipitationreaction inaqueoussolutionofbarium hydroxideandsulfuricacidwithethyleneglycolasamodifying agent，andthencalcinedatvarioustemperatures．TheobtainedBaSO4wasusedascatalystcarriersforpolystyrene (PS)hydrogenation，andBaSO4supportedpalladium (Pd)catalystswithPdcontentof5wt％werepreparedbyusing impregnationmethod．N2physisorption，transmissionelectronmicroscopy X-raydiffractionandkineticsstudieswere ， usedtoinvestigatetheeffectofcarrierstructureonthedispersionandgeometriclocationofactivemetalandtheir catalyticactivitiesinPShydrogenation．Itwasfoundthattheporestructureofcarrierplayedanimportantroleinthe dispersionand1ocationofPdgrains．TheactivationenergyvaluesofrallthePd／BaS0dcatalystswerearound49．1 kJ／mol，whilethepre—exponentialfactorofrPd／BSC．6H wasmuchhigherthanothers．ThePd／BSC一6H without mesoporeshadPd grainsdepositedon the externalsurfaceofthe carrier，and exhibited betteractivity than the mesoporouscatalysts．ItisindicatedthattheutilizationofPd／BSC一6H canreducehteporediffusionofPScoilsand enabledmoreactivesitestoparticipateinthePShyrdogenation． Keywords：polystyrenehyrdogenation；carrierstructure；supportedcatalyst Commercialpolystyrene (PS)isoneofthemost thehydrogenati