Monodisperse Ultra-Large-Pore Silica Coated Polystyrene Core-Shell Microbeads via Layer-by-Layer Assembly for Nano-Micro Composite.pdfVIP

工 卫 f▲上 ，f 1 工U I， D0I10．1007／s12209—015—2642-2 oFTIANJIN UNIVERSITY M onodisperseUltra-La e-PoreSilicaCoatedPolystyrene Core．ShellM icrobeadsviaLayer-by-LayerAssembly forNano．．M icroComposite XieChuang(谢 闯)，LiuYiqing(刘逸卿)，LiHongda(李泓达)，HaoHongxun(郝红勋)， WangYongli(王永莉)，YinQiuxiang(尹秋响)，WangJingkang(王静康) (SchoolofChemicalEngineeringandTechnology，TianjinUniversity，Tianjin300072，China) ◎TianjinUniversiytandSpringer—VerlagBerlinHeidelberg2015 Abstract：Polystyrene(PS)@Si02core—shellmicrobeadswithlargeporeandlargeparticlesizewereprepraedvia layer-by-layer(LBL)assembly techniquef0rpotentialapplicationsinnano—microcomposites．Negativesilica nnaoparticlessynthesizedviamodifledStObermethodandcationicpoly(diallyldimethylammonium chloride)were alternatelyadsorbedonthesurfaceofmicrobeads．Zetapotential，size，nadmorphologyofthemicrobeadswere monitoredduringLBL assemblyprocesstoensurethesuceessfialdepositionofsilican：anoparticles．Theporous shellwascharacterizedusingnitrogenadsoprtionanddesoprtionanalyses，nadthesurfacearea，volumeanddiame． terofhteporeswerederived．Itisfoundthattheporousshellthicknessnadthepore sizeCallbetunedbychnaging thecoatingtimesofsilicananoparticles．F。inally，PS@Si02core—shellmicrobeadswith5．pinPSsolidcorenad 350nlrlmesoporousshell(mena BJI-Iporediameteris~27rim)wereusedtoloadCdSe／ZnSqunatumdots(QDs)． The 。fluorescence microscopic image nad the：opticalamplification ofthe QDs．embedded microbeads (QDBs)indicatehtathteas-prepraedcore-shellmicrobeadscarlprovideadequatespaceforQDsnadmaybeuseful for erapplicationofnnao-microcomposites． Keywords：lrageporemesoporoussilica；core-shellstructure；microbeads；layer-by-layerasse