4-乙酰基-2-硝基苯甲醛的简便合成有机化学.pdfVIP

2007 年第 27 卷 有 机 化 学 Vol. 27, 2007 第 11 期, 1414～1419 Chinese Journal of Organic Chemistry No. 11, 1414～1419 ·研究简报· 脱氢松香酸甲酯类衍生物的合成 a a a,b *,a 冯少波 雷 茜 张 业 王恒山 潘英明*,a 吴 强a 童碧海a a ( 广西师范大学化学化工学院 桂林 541004) (b 桂林师范高等专科学校化学与工程技术系 桂林 541004) 摘要 以脱氢松香酸甲酯为原 , 经溴代、硝化、还原、重氮化等步骤合成了 6 种 12 位取代的脱氢松香酸甲酯衍生物, 研究了 12 位上不同取代基对它们紫外、荧光性质的影响; 然后再分别以得到的 12-氯脱氢松香酸甲酯和 12-溴脱氢松香 酸甲酯为起始物, 经双硝化、氧化、脱异丙基硝化等步骤合成了一系列重要的脱氢松香酸甲酯卤代硝化衍生物, 并对 12-氯脱氢松香酸甲酯、12-溴-13,14-二硝基脱氢松香酸甲酯的单晶进行了 X 射线衍射表征. 关键词 合成; 脱氢松香酸甲酯; X 射线单晶衍射; 紫外吸收; 荧光吸收 Synthesis of the Derivatives of Methyl Dehydroabietate FENG, Shao-Boa LEI, Qiana ZHANG, Yea,b WANG, Heng-Shan*,a PAN, Ying-Ming*,a WU, Qianga TONG, Bi-Haia a ( College of Chemistry and Chemical Engineering, Guangxi Normal University, Guilin 541004) (b Department of Chemistry and Engineering Technology, Guilin Teachers College, Guilin 541004) Abstract Starting from methyl dehydroabietate, six derivatives of methyl 12-substituted-dehydroabietate were synthesized through several steps, such as bromation, nitration, reduction and diazotization, and the ef- fect of the different groups of methyl 12-substituted-dehydroabietate derivatives on their UV and fluores- cence prop