3-戊烯腈在零价镍催化体系中的平衡反应有机化学.pdfVIP

DOI: 10.6023/cjoc1107202 研究简报 有机化学 Chinese Journal of Organic Chemistry NOTE 3-戊烯腈在零价镍催化体系中的平衡反应 董建勋a,b 石玉坤a 胡晓静a 冯晓燕b 宋娟娟a 丁真贞a 刘向明a 黄唯平*,a (a 南开大学化学系 天津 300071) (b 中国平煤神马能源化工集团尼龙化工公司 平顶山 467013) 摘要 在探索 3-戊烯腈氢氰化合成己二腈反应的机理过程中, 发现 3-戊烯腈在零价镍体系中可能同时存在多个平衡反 应, 在不外加氰化氢条件下, 3-戊烯腈可以生成甲基戊二腈和己二腈. 采用零价镍、膦配体和无水 ZnCl2 组成的催化体 系研究了该反应过程, 考察了反应温度和配体的影响, 并采用原位红外对反应进行监测, 提出了可能的反应机理. 关键词 零价镍; 3-戊烯腈; 2- 甲基戊二腈; 己二腈; 反应平衡 Nickel(0)-Catalyzed Equilibrium Reaction of 3-Pentenenitrile Dong, Jianxuna,b Shi, Yukuna Hu, Xiaojinga Feng, Xiaoyan b Song, Juanjuana Ding, Zhenzhena Liu, Xiangminga Huang,Weiping*,a a ( College of Chemistry, Nankai University, Tianjin 300071) b ( China Pingmei Shenma Energy and Chemical Group Nylon Chemical Company, Pingdingshan 467013) Abstract The equilibrium reaction of 3-pentenenitrile was carried out in the system containing Ni(0), P-ligand and anhydrous ZnCl . The equilibrium state of 3-pentenenitrile was affected by factors such as reaction temperatures and different ligands, 2 which were investigated. The FTIR-ATR was used to monitor the reaction process of 3-pentenenitrile turning into 2-methylglutaronitrile and adiponitrile in absence of HCN and the possible reaction mechanism was proposed. Keywords zero-valent nickel; 3-pentenenitrile; 2-methylglutaronitrile; adiponitrile; r