基于Schiff-Base反应的成环策略及应用有机化学.pdfVIP

2010 年第 30 卷 有 机 化 学 Vol. 30, 2010 第 8 期, 1142～1155 Chinese Journal of Organic Chemistry No. 8, 1142～1155 ·综述与进展· 基于 Schiff-Base 反应的成环策略及应用 张家强 贾春阳* ( 电子科技大学微电子与固体电子学院 电子薄膜与集成器件国家重点实验室 成都 610054) 摘要 基于 Schiff-base 反应的大环化合物是近些年来超分子领域研究的热点. 这些大环化合物不但在传感器、功能材 料等领域发挥着重要的作用, 而且在自组装研究领域具有重要的意义. 从模板法和非模板法两方面分析了一些具有代 表性 Schiff-base 大环的合成, 发现, 不但具有合适半径和构型的离子可以作为成环反应的模板, 而且强烈的分子内氢 键也能有效地驱动成环反应. 同时, 对于该类大环分子合成所面临的问题及发展方向进行了评述和预测. 关键词 大环化合物; Schiff-base 反应; 模板; 氢键 Synthetic Strategies and Applications of Macrocycle Molecules Based on Schiff-Base Reaction Zhang, Jiaqiang Jia, Chunyang* (State Key Laboratory of Electronic Thin Films and Integrated Devices, School of Microelectronics and Solid-State Electronic, University of Electronic Science and Technology of China, Chengdu 610054) Abstract New macrocycle molecules based on Schiff-base reaction have been attracted lots of interest in recent years. These macrocycle molecules play important role not only in the research fields of chemical sensors, functional materials etc., but also in the research field of self-assembly. In this paper, the synthetic strategies of macrocycle molecules will be studied from the results of macrocycle synthesis with templates and without templates. It was found that not only metal ions with suitable diameters and conformations could be as templates for construction of macrocycle molecules, but also the strong intramolecular hydrogen bonds