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Availableonlineatwww.sciencedirect.corn
禅 艚
嗨
静 :ScienceDirect RAREMETALS
RAREMETALS,VoL27,No.2.Apr2oos,p.153
Sorptionbehaviorofiminodiaceticacidresinforindium
XIONGChunhuaandYAO Caiping
DepartmentofAppliedChemistry,ZhefiangGongshangUniversity,Hangzhou310035,China
Received8February2007;receivedinrevisedform 19March2007;accepted25March2007
Abstract
Il1(Ⅲ)wasquantitativelyadsorbedbyiminodiaceticacidresin(IDAAR)inthemediumofpH=4.52.Thesatticallysaturatedsorptioncapac—
i ofIDAAR is235.5mgg·一.1.0molL·-HC1cna beusedasaneluant.Th eelutionefficiencyis97.9%.Th eresincna beregeneratedand
reusedwithoutapparentdecreaseofsorptioncapacity.Th esorptionrateconstantisk298 1.94x10 s一.Th eapparentsorptionactivation
energyofIDAARfor/n(m)is20.1kJ’mol一.ThesorptionbehaviorofIDAARforIn(1/I)obeyshteFreundlichisohterm.Theenthalpy
chna geisAH=17.2kJ.otol-.
Keywords:iminodiaceticacidresni;indium(III);sorption;activationenergy;enhtalpychnage
UV一2550UV—VISIBLE specrtophotometer,MettlerTolde o
1.Introduction
Delta 320 pH meter,DSHZ一300A temperature constant
Thesynthesis,characterizationandsorptionpropertyof shakingmachine,THZ—C一1temperatureconstantshaking
polymeric materialshavebeen published in recentyeras machine,SK5200LH ulrtasonic cleaningnisturment,Ele—
[1—13】.Iminodiaceticacidresin(IDAAR)isanovelpoly— mentalAnalyzerVarioEL,na dIRNicolet380.
meric material containing the functional group
N(CH2COOH)2.Ithasnotonlyprotonshtatcna ex
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