直接甲醇燃料电池的单电池实验测试及性能优化_魏永生.pdfVIP

34 6 Vol. 34 No. 6 20 10 12 JOURNAL OF BEIJING JIAOT ONG UNIVERSITY De . 20 10 : 1673-0291( 2010) 06-0090-05 1 2 1 1 1 魏永生, 朱 红, 郭玉宝, 郭志军, 张新卫 ( 1. , 100044; 2. , 100029) : 以新型阻醇材料Na Ti O / Nafion 复合膜为质子交换膜, 利用热压 制备膜电极( M EA) , 2 3 7 对直接甲醇单电池进行测试. 考察了电池温度阴极加湿温度甲醇浓度甲醇流速和空气流速5 个 参数对直接甲醇燃料电池极化曲线性能的影响. 实验结果表明, 电池温度对电池性能的影响较为明 显, 提高电池温度有利于得到较好的电池性能. 甲醇浓度对电池性能影响也比较明显, 较低甲醇浓 度有利于提高电池性能. 甲醇流速和空气流速对电池性能的影响较小, 阴极加湿温度对电池性能几 乎没有影响. 通过分析优化, 该直接甲醇燃料电池的电池性能最佳工作条件是在80 情况下, 低电 流密度工作区采用较低浓度甲醇溶液, 高电流密度工作区采用高浓度甲醇溶液. : 直接甲醇燃料电池; 质子交换膜; Na2Ti3O7/ Nafion; 极化曲线 : TK91 : A Experimental Test and Performance Optimization of Single Cell in Direct Methanol Fuel Cell 1 2 1 1 1 WEI Yong sheng , ZH U H ong , G UO Yubao , G UO Zh ij un , ZH A N G X inw ei ( 1. S hool of S ien e, Beijing Jiaotong University, Beijing 100044, China; 2. S hool of S ien e, Beijing University of Chemi al T e hnology, Beijing 100029, China) Abstract: With new omposite membrane materials of Na2Ti3O7/ Nafion for proton ex hange mem- brane, Membrane Ele trode Assembly ( MEA) was prepared using hot-pressing method, and had been tested in single dire t methanol fuel ell. Operation parameters of ell temperature, athode humidify- ing temperature, methanol on entration, methanol flow rate and air flow rate have been employed to study on the effe t of dire t methanol fuel ells polarization urve. Experimental results show that the effe t of ell temperature on the ell performan e is obvio