Ni-loaded Catalyst Containing Activated Clay for Maleic Anhydride Hydrogenation to Succinic Anhydride.pdfVIP
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Ni-loaded Catalyst Containing Activated Clay for Maleic Anhydride Hydrogenation to Succinic Anhydride.pdf
ChinaPetroleumProcessingandPetrochemicalTechnology
CatalystResearch 2011,Vo1.13,No.4,PP35—40 December30,2011
Ni-loadedCatalystContainingActivatedClayforM aleic
AnhydrideHydr0genati0ntoSuccinicAnhydride
TianW eiping;GuoShaofei;ShiLi
(TheStateKeyLaboratoryofChemicalEngineering,EastChinaUniversityof
ScienceandTechnology,Shanghai200237)
Abstract:Inthiswork,thehydrogenationofmaleicanhyrdidetosuccinicanhydrideinhtepresenceof5m%Ni/claycata-
lystswasinvestigated.Thesecatalystswerechraacterizedbyx—raydiffraction(XRD),H2temperatureprogrammedreduc—
tion(TPR)andthermogravimetricnaalysis(TGA)techniques.TheXRDnadTPRstudiesshowedthatNiwaspresentas
Nionthesupport,whichindicatedthattherewerenoelementalnickelfNi”)nadNi2O3speciesintheunreducedsamples.
Increasingofcalcinationtemperatureto650。C leadstodestructionofthesupportstructureobservedinTGA,whilethecat-
alystsamplecalcinedat550℃ exhibitsbetterperff)rmancesthanothersamples.Theidealconversionofmaleicanhydride
(97.14%)andselectivityofsuccinicanhyrdide(99.55%)wererealizedatareactiontemperatureof180℃nadaweight
b岫+..
hourlyspacevelocityof4h underareactionpressureof1M Pa.
.
砌m
Keywords:maleicanhydride;hyrdogenation;succinicanhyrdide;nickel
1 Introduction 1,4-butanediol(BDO)andtetrahydrofuran(THF),are
importantintermediatesorsolven
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