黄应胡论文(TiOCNTs复合材料光催化性能研究)二稿.解读.docVIP

TiO2/CNTs复合材料光催化性能研究 黄应胡 （湛江师范学院化学科学与技术学院，湛江 524048） 摘 要:采用水热法制备TiO2负载碳纳米管光催化剂，通过改变水热反应时间，反应温度，乙酸用量，乙醇用量等影响因素来探究水热制备TiO2/CNTs复合材料的最佳条件。采用差示扫描量热法（DSC）、傅里叶变换红外光谱（FTIR）、扫描电子显微镜 （SEM）、X射线衍射(XRD)对TiO2/CNTs复合材料进行表征。测试了不同水热条件和不同CNTs质量分数制备的TiO2/CNTs复合材料对甲基橙光催化降解性能，同时考察了甲基橙溶液PH值对光催化性能的影响。光催化测试结果表明：在水热条件组合为温度140℃、时间16h、乙醇用量20ml、乙酸用量20ml，CNTs质量分数为5%时制备出来的TiO2/CNTs复合材料光催化性能最好，并且当甲基橙溶液为中性时，TiO2/CNTs复合材料具有最佳的降解效果。 关键词：纳米TiO2 ；碳纳米管；水热法；光催化降解；甲基橙 The Study on photocatalytic performance of TiO2 / CNTs composites HUANG Yinghu (Department of Chenical Science and Technology, Zhangjiang Normal University, Zhangjiang 524048) Attract：A photocatalyst of nano TiO2 loaded with carbon nanotubes was prepared by hydrothermal methodthe optimum condition of preparation of TiO2 / CNTs composites was studied by changing the reaction conditions such as hydrothermal temperature, dosage of acetic acid, dosage of ethanol and other influence factors. Differential Scanning Calorimetry,,Fourier transform infrared spectroscopy, Scanning Electron Microscope, X-ray Diffraction were employed to determine the structure and surface properties of the TiO2 / CNTs composites. Methyl orange was selected as the target pollutants, photocatalytic properties of composites prepared on different hydrothermal conditions and with different CNTs mass fraction were analyzed, PH of methyl orange solution were also discussed. Photocatalytic test results show that the TiO2 / CNTs composites with best photocatalytic properties when hydrothermal condition combination of temperature 140 ℃, time 16 h, 20 ml ethanol, acetic acid 20 ml, CNTs mass fraction 5% and when the methyl orange solution is neutral, the degradation of TiO2 / CNTs composites material has the best effect. Key words: Nano TiO2；carbon nanotubes；Hydrothermal method；Photocatalytic degradation ；Methyl orange 1 引言 我国已经成为世界上最大的加工制造基地。随着经济的高速发展，我们的环境问题越趋严重，特别是水资源的污染时刻影响着我们的生活。目前，治理水体污染通常采用是先进性预处理，再进行二级处理。预处理主要包括沉淀法，吸附法等，二级处理主要包括好氧法厌氧法等。处理方法缺点明显，大部分处理仅仅是有机物状态的