《聚多巴胺修饰电极的电化学聚合》.ppt

实验数据报告 李晓涵 2015.5.5 聚多巴胺修饰电极的电化学聚合 图1 多巴胺电聚合循环伏安图 Fig.1 The CVs curves for polymerization of 1.0 mmol/L DA obtained at GC electrode in a 0.1mol/L H2SO4, Sweep rate: 50 mV/s, sweep cycles: 10. 不同电极的CV图 图2 不同电极在1.0 mmol/L DA+0.1 mol/L H2SO4溶液中的循环伏安图 Fig.2 Cyclic voltammograms in 1.0 mmol/L DA+ 0.1 mol/L H2SO4 at scan rate 0.1 V/s on bare GCE (a), electrochemically pretreated GCE (b), PDA/GCE (c) and PDA/GN/GCE (d) PDA/GCE和PDA/GN/GCE的CV图 图3 PDA/GCE和PDA/GN/GCE在空白H2SO4溶液中的循环伏安图 Fig.3. CVs of PDA/GCE(a) and PDA/GN/GCE(b) in 0.1 M H2SO4, Sweep rate: 0.1 mV/s. UA在不同电极上的CV图 图4 UA在不同电极上的循环伏安图 Fig.4 Cyclic voltammograms of 80 μmol/L UA in 0.1 mol/L PBS (pH 6) at scan rate 0.1 V/s on bare GCE (a), electrochemically pretreated GCE (b), PDA/GCE (c) and PDA/GN/GCE (d). UA氧化峰电流与溶液浓度的关系 图5 UA氧化峰电流与溶液浓度的关系 Fig.5. (A) Relationship between oxidation peak current and concentration of UA in 0.1 mol/L PBS (pH 6). CUA: 1.0, 2.0, 4.0, 6.0, 8.0, 10, 20, 40, 60, 80, 100, 200, 400, 800 μmol/L; Insert: calibration curve of UA on the PDA/GN/GCE. pH的影响 图6 UA峰电流与溶液pH的关系 Fig.6. Relationship between peak current and pH of UA a: pH3.0, b: pH4.0, c: pH5.0, d: pH6.0, e: pH6.8, f: pH8.0. 扫速的影响 图7 UA氧化峰电流与扫描速率平方跟的关系图 Fig.7. Relationship between oxidation peak current and the square root of the scanning rate ν (a→g):20, 60, 100, 120, 180, 240, 300 mV/s; 80 μmol/L UA, PBS(pH6) 干扰实验 图8 PDA/GN/GCE在含有100 μM AA和不同浓度UA溶液中的DPV图 Fig.8 DPV profiles at PDA/GN/GCE in 0.1 M PBS (pH 6) containing 100 μM AA and different concentrations of UA from 2.0 to 400 μM. Inset: plots of the anodic peak current as a function of UA concentrations. * *