铱钽钛金属氧化阳极的电化学特性.doc

铱钽钛金属氧化物阳极的电化学特性 王廷勇　许立坤　陈光章 摘　要：采用热分解方法在钛基体上制备铱钽钛金属氧化物阳极，用扫描电镜对阳极涂层显微形貌进行分析，通过强化电解寿命试验、开路电位测试、消耗率试验及循环伏安曲线研究了金属氧化物阳极的电化学性能.SEM分析结果表明铱钽钛金属氧化物阳极涂层呈现多孔多裂纹形貌结构.随阳极涂层组成不同，涂层显微形貌表现出很大差异，这种差异直接影响阳极电化学性能.电化学性能试验结果表明铱钽钛金属氧化物阳极在酸性介质和海水中具有良好的电化学稳定性和电化学活性.此外，铱钽钛金属氧化物阳极在海水中的消耗率很低，属于不溶性的阳极材料，作为外加电流阴极保护用辅助阳极具有广泛的应用前景.关键词：电化学稳定性,电化学活性,开路电位,循环伏安分类号：TG 174　文献标识码：A文章编号：1006-3471(2000)01-0072-06 Electrochemical Characterization of Ir-Ta-Ti Metal Oxide Coated Titanium Anodes WANG Ting-yong,XU Li-kun,CHEN Guang-zhang(Qingdao Branch of Luoyang Ship Material Research Institute,Qingdao 266071,China) Abstract:Ir-Ta-Ti metal oxide coated titanium anodes of variable composition were prepared by thermal decomposition.Their micro morphorogies and electrochemical properties were characterized by scanning electron microscope,open circuit potential,cyclic voltammetry,consumption rate measurements and accelerated life test.The SEM results indicated that all coatings were of a porous and cracked-mud microstructure influenced greatly by the composition of coatings.The electrochemical measurements showed that the Ir-Ta-Ti ternary oxide-coated anodes exhibited excellent electrochemical activity and electrochemical stability in both acidic media and seawater which were affected by the composition and microstructure of the coatings.Owing to good corrosion resistance and low consumption rate in seawater,metal oxde coated anodes belong to insoluble material,and can be potentially applid in impressed current cathodic protection systems as an anode.Key words：Electrochemical activity,Elcetrochemical stability,Open-circuit potential,Cyclic voltammetry▲ 　　外加电流阴极保护用的辅助阳极应具备排流量大、使用寿命长及成本低等特点.金属氧化物阳极是一种尺寸稳定型阳极，由于具有耐蚀性好、消耗率低、电化学活性高，而且价格较低等优点，而逐渐被用作外加电流阴极保护用辅助阳极材料［1～2］.又因采用贵金属铱作为电极材料具有高的电化学活性和耐蚀性能，因而受到普遍重视［3～5］.　　本文选用贵金属铱作为活性组元，阀金属钽和钛作为惰性组元，采用热分解方法在钛基体上制备了铱钽钛金属氧化物阳极.通过强化电解寿命试验、开路电位测试、消耗率试验及循环伏安曲线研究了金属氧化物阳极的电化学行为，同时应用扫描电镜对阳极涂层显微形貌进行了微观分析. 1　实　验 1.1　金属氧化物阳极的制备　　阳极基体选用工业用纯钛TA2，对基体进行除油处理及草酸刻蚀.按表1中的成份配比将H2IrCl6.H2