antimicrobialphotocatalyticsurfacetreatmentonstainlesssteel.docVIP

不銹鋼之光觸媒抗菌表面處理 Antimicrobial Photocatalytic Surface Treatment on Stainless Steel *鍾啟仁 1, 2 林欣熠 1 謝國章 1 何主亮 1 Chi-Jen Chung1, 2 Hsin-I Lin1 Kuo-Chang Hsieh1 Ju-Liang He1 摘要 applied extensively in form of coatings, in 二氧化鈦(TiO2)以其無毒、催化活性高及 particular for its unique properties such as high 自潔能力強的特性，已被廣泛的發展應用，然 photocatalytic activity, strong self-cleaning 其諸多鍍膜製程卻一直無法被證實其抗菌能 ability and non-toxicity. This could potentially 力。本研究採用電弧離子鍍法被覆TiO2鍍膜， be applied on stainless steel for antimicrobial 以醫療器材常用之AISI 304不銹鋼為基材，藉 purpose. An arc ion plating method that is 由不同施鍍參數，期望TiO2光觸媒鍍膜能改善 commonly used for protective coatings, is 不銹鋼之抗菌能力，並透過其對亞甲基藍溶液 proposed to produce TiO2 films on medical 的光觸媒效能測定以及JIS Z2801:2000標準工 grade AISI 304 stainless steel. Antimicrobial 業規範抗菌能力之評估，瞭解光觸媒效能及抗 efficacy is expected by proper control of coating 菌能力之關聯性。 parameters. Photocatalytic performance of the 研究結果顯示；在適當施鍍參數下，以電 deposited specimens is tested with methylene 弧離子鍍可成功的在不銹鋼上製備出具有銳 blue solution, and antimicrobial efficacy is 鈦礦相結構之柱狀TiO2鍍膜。隨著沉積時間增 evaluated through the use of JIS Z2801:2000 加TiO2鍍膜逐漸增厚，晶體結構也由金紅石相 industrial standard for better understanding the 轉為銳鈦礦相為主，厚度超過2.5 μm以上時光 relation between photocatalytic effect and 觸媒效率近乎最大值，對應出抗菌活性R值在 antimicrobial efficacy. μm以上時近乎最大值3.1。隨著沉積氧氣分 The experimental result shows that 壓增加，鍍膜除了結晶性增加之外，銳鈦礦相 columnar TiO2 film with an anatase phase 也隨之增加，且光觸媒效率逐漸增加，其抗菌 structure can be prepared successfully on 活性R值也逐漸攀升到近乎最大值3.1。證實了 stainless steel within a proper coating parameter 具有光觸媒特性之銳鈦礦相TiO2鍍膜才是影 range. By increasing deposition time, the film 響抗菌活性的主因，使不銹鋼表面抗菌效果獲 initially consist of mainly rutile phase followed 得大幅度提升。 by anatase phase at later stage. Over a thickness 關鍵詞：二氧化鈦、電弧離子鍍、不銹鋼、抗 菌。 of 2.5 μm, photocatalytic efficiency of the deposited film presents the largest value, at the same time the antimicrobial activity (R) reaches Abstract Titanium dioxide has been developed and the maximum value of 3.1. In addition to this, oxygen par