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The aging process of hydrogel contact lenses studied by 1H NMR and DSC methods.pdf

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European Polymer Journal 76 (2016) 135–146 Contents lists available at ScienceDirect European Polymer Journal journal homepage: /locate/europolj The aging process of hydrogel contact lenses studied by 1H NMR and DSC methods A. Woz′ niak-Braszak ?, M. Kaz′ mierczak, M. Baranowski, K. Ho?derna-Natkaniec, K. Jurga High Pressure Physics Division, Faculty of Physics, Adam Mickiewicz University, Umultowska 85, 61-614 Poznan, Poland article info Article history: Received 9 November 2015 Received in revised form 15 January 2016 Accepted 24 January 2016 Available online 26 January 2016 Keywords: Contact lens Hydrogel Free water contact Bound water content Dispersion of times relaxation 1H NMR methods abstract This paper presents the comparative study of molecular dynamics and of the thermal properties of the virgin commercial monthly hydrogel contact lenses Bausch Lomb So?ens 59 and the lenses worn for 1, 2, 3 and 4 weeks. The lenses were made from the hila?lcon B material, which was a hydrophilic copolymer of poly(2-hydroxyethyl methacrylate) pHEMA and poly(N-vinyl pyrrolidone) PVP, containing 59 wt.% of water. The 1H NMR onresonance and off-resonance techniques have been carried out to study the molecular dynamics of the water contained in soft contact lenses. The measurements were carried out using a homemade pulse spectrometer operating at the frequency of 30.2 MHz at temperature 303 K. On the basis of the dispersion of the spin–lattice relaxation rates R1q = 1/T1q in the rotating frame the correlation times sc of the water molecules were estimated. A new method for measuring the motion parameters, based on the value of the equilibrium magnetization in the effective ?eld Be was described. To analyze NMR off-resonance results a model-free approach with Lipari–Szabo spectral density function was used to determine the order parameter S2 and the effective correlation time se. The thermal properties of hydrogel contact lenses have been characterized using differential scanni