重油催化裂化沉降器结焦过程的模型化分析.pdfVIP

重油催化裂化沉降器结焦过程的模型化分析 王 刚 蓝兴英 徐春明 高金森* （中国石油大学（北京）重质油国家重点实验室，北京昌平 102249 ） 摘 要：在详细研究重油催化裂化工业装置沉降器内不同操作条件下油气重组分汽 化率及油浆生焦规律的基础上，建立了可有效确定沉降器内重组分汽化率的 UNIFAC 模型和油浆重馏分生焦率模型。然后利用欧拉模型对沉降器内部的流动、 传热、传质情况进行详尽模拟，揭示了油气达到重组分冷凝、结焦的沉降器内部环 境条件，结合颗粒轨道模型、油浆汽化率模型和油浆重馏分生焦率模型，可确定沉 降器内重油液滴的产生源、捕获位置、捕获率以及主要结焦部位和结焦量，从而有 效的对重油催化裂化工业装置沉降器系统的运转进行诊断。 关键词: 重油催化裂化；沉降器；结焦；模型化 Modeling of Coke Formation in Disengager of Residue Fluid Catalytic Cracking Units WANG Gang, LAN Xingying, XU Chun-ming, GAO Jin-sen* (State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing 102249 ) Abstract: Based on the investigation of the vaporization ratio of heavy oil fraction in residue fluid catalytic cracking (RFCC) disengager at different operating conditions and the coke formation of slurry, the UNIFIC model to determine the vaporization ratio of oil vapor and the coking model of slurry in liquid phase are established. The solid-gas flow, heat transfer, and mass transfer in the disengager was simulated and analyzed in detail and the inner condition of the disengager for oil vapor condensation and coking were explored. In combined with particle-trajectory model, vaporization model and coking model of slurry, the source, the capture position and the quantity of liquid droplets condensed from heavy oil fractions in disengager, as well as the coking position and quantity, can be determined. All these models can be applied to the diagnosis for the operation of the disengager in RFCC units. Key words: RFCC; disengager; coke formation; modeling 1 前 言 重油催化裂化装置沉降器内结焦问题严重影响了装置的长周期运行，因结焦而 导致的非计划停工给炼油企业带来巨大的经济损失[1,2] 。因此，抑止或减少沉降器结 焦已经成为催化裂化技术急需解决的问题。国内外研究者进行了大量观测、研究和 分析，在沉降器结焦的机理和原因等方面取得了一定的成果[3-6] ，探索出了一些抑制 沉降器结焦的措施[