扫描微电极法研究钢筋局部腐蚀行为.pdfVIP

第 11 卷第 1 期 2008 年 2 月 建筑材料学报 JOURNAI. OF BUJLDlNG MATERJALS 文.编号，1007-9629(2008)0 1 -0033一05 扫描微电极法研究钢筋局部腐蚀行为 杜荣归1.2，李彦1 ，2，刘玉1·2，林昌健1.2 (1.厦门大学化学化工学院，福建厦门 361005 ， Z. 团体表面物理化学国家重点实验室 ，摇建厦门 36100日 Yol. Il, No.l Feb. .2008 摘要 z 应用扫描微电极法原位测量了模拟混宿在土孔~液中钢筋表面很区的电位分布，并 综合动电位极化曲线的测量，研究了钢筋的局部腐蚀行为Jl..模拟混凝土孔隙浅 pH 位和 CI- 浓度.tt它的影响.结果表明，在饱和 Ca(OH)z 溶液中，钢筋处于钝态，其表面微区电 位分布为动态平衡;溶液的 pH í直降低和外加一定浓度的 CI-后，钢~~1i1徽区也位分布 随之变化.当*-1i1微区电位分布 III 珑固定的突出电位峰时，钢筋发生了点腐蚀.在 pH= 12. 00，外加 CI- 浓度为 0.05 mol/L 或 pH 位降至 10.16 的 Ca(?H )z 溶液中，钢筋表面 去钝化，发生腐蚀. 关键词:钢筋;局部腐蚀 s 扫描微电极z 缓蚀剂 中图分类号，0646 文献标识码.A Study on Localized Corrosion Behavior of Reinforcing SteeJ by Scanning Microelectrode Technique DU R ong-gui 1 ? 2 , LI Yan 1?2 , LIU Yu川 ， LIN Chang-jian 1.2 (1. College of Chemistry and ChemicaJ Engineering. Xiamen University. Xiamen 361005. China, 2. 51ate Key La切ratory for Physical Chemistry o( Solid 5urfaces. Xiamen 361005. China) Abstract. In thís work , the scanning mícroelectrode technique and potentiodynamic polarization were used to st udy the localized corrosion behavior of the reinforcing steel in simulated concrete pore solutíon with different p H values and chloride íon concentrations. lt has been found that the reinforcíng steel bar exhibits different corrosion characteristics in different conditíons. There are some unstable micro-pitting nuclei on the surface of the 5teel in pure saturated Ca(OH h solution and the steel remains passívated. However , the potential dístríbution on t he steel 5urface changes with the addition of CI- or/and the reduction of p H value in the solution. The pitting corrosion of the 5teel occurs quíckly when there are some obvious stable potential peaks on the 5teel 5urface and the height of one or some maxímum potentíal pωks increases wíth t íme. Steel depassivation initiates and the corrosion takes place when addítíonal C1- concentration reaches O. 05 mol/L in the Ca(üH)z solution with pH = 12.00 or the pH of the solution falls to 10. 16. Key w