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Kinetic study on deep dephosphorization treatment of liquid steel by BaO-based fluxes.pdf

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Kinetic study on deep dephosphorization treatment of liquid steel by BaO-based fluxes

JournalofUniversityofScienceandTechnologyBeijing Volume11,Number December20O4,Page494 Kinetic study on deep dephosphorization treatment of liquid steel by BaO-based fluxes Zhihong Tian”，Yanyong Guo Kaike Cai Liqun Ai and Huien Shi 1)Metalurgical and Ecological Engineering School，University of Science and Technology Beijing，Beijing 100083，China 2)Metalurgical Department,Heibei Institute of Technology,Tangshan 063009，China (Received 2004-02—16) Abstract：Laboratory study was carried out on deep dephosphofization of liquid ste l by BaO-based fluxes at 1600。C to achieve ul— tra low phosphorus level in the ste1．A dynamic model of dephosphofization of liquid stel by BaO—based fluxes was established ． According to the model，the controlling step of dephosphofizafion by BaO—based fluxes was the mass-transfer of phosphorus in stel phaseunderthe condition oflow phosphorusliquid ste1．Itis estimated thatthe apparent rate constantofdephosphorizationbyBaO— based fluxes was 0．4x10-3-8．2~10- ~(cm2·s and the mass—trans~r coefficient of phosphorus in bulk steel was 0．025—0．04 cm／s． Key words：BaO—based fluxes treatment；dep dephosphorization；dynamic model；limiting step 1 Intruduction In order to obtain ultra．1ow phosphorus steel，we needs dephosphorization in the secondary refining process besides the deph0sph0rizati0n of hot metal and dephosphorization during the process of stee1． making．At present，CaO．based fluxes are studied widely for dephosphorization【1，2】．Comparing with CaO．CaF，flux，Bao—CaF，flux has a higher phosphate capacity and a lower PO， activity coeficient．At 1400。C．the phosphate capacity of Bao．CaF2 flux ran ges from 1024 to 10五 while that of CaO．C心、flux ran ges from 10 0 to lO24． Bao is a strong basic oxide which can increase the basicity ofthe fulx and prevent rephosphorization in molten meta1．Adding BaO to CaO．based fluxes can increase the phosphate capacity andlowerthePO， activity coeficientofthefluxes【3， 41．BaO．based fluxes are mainly used to the dephos— phori