水蒸气对石灰石循环煅烧碳酸化捕集二氧化碳的影响.pdfVIP

第34 卷 第8 期 中 国 电 机 工 程 学 报 Vol.34 No.8 Mar.15, 2014 1224 2014 年3 月15 日 Proceedings of the CSEE ©2014 Chin.Soc.for Elec.Eng. DOI ：10.13334/j.0258-8013.pcsee.2014.08.002 文章编号：0258-8013 (2014) 08-1224-07 中图分类号：TQ 534 水蒸气对石灰石循环煅烧/碳酸化捕集二氧化碳的 影响 王春波，周兴，郑之民，崔彩艳，陈亮 (华北电力大学能源动力与机械工程学院，河北省 保定市 071003) Influence of Steam on the Limestone Calcination/Carbonation Looping Cycle for CO Capture 2 WANG Chunbo, ZHOU Xing, ZHENG Zhimin, CUI Caiyan, CHEN Liang (School of Energy and Power Engineering, North China Electric Power University, Baoding 071003, Hebei Province, China) ABSTRACT: By means of a customized thermogravimetric 关键词：水蒸气；石灰石；煅烧/碳酸化；循环反应；捕集 analysis system that can measure the weight change of samples CO2 转化率 at constant temperature, the influence of steam on the 0 引言 limestone calcination/carbonation cyclic reactions were studied. Results show that steam reduces the sorbent activity [1] CO2 是引起全球气候变暖的主要温室气体 。 during calcination, while it greatly increases carbonation 燃煤电厂排放的 CO2 约占世界 CO2 总排放量的 conversion ratio during the carbonation (for instance, the ratio 33%~40%，我国甚至高达73%[2] 。钙基吸收剂循环 at the eighth cycle is 29.43% with 20% steam, but only 19.46% without steam). The carbonation ratios of sorbents are very 煅烧/碳酸化捕集 CO2 是目前最受关注的针对燃煤 电厂CO [3] similar whenever both calcination and carb