Dispersed liquid-liquid micro-extraction - floating solvent curing - Determination of sediment decabromodiphenyl ether.docVIP

 PAGE \* MERGEFORMAT 17 Dispersed liquid-liquid micro-extraction - floating solvent curing / Determination of sediment decabromodiphenyl ether Of: Jian Ying-Hong Hu Yan Wang Ting Liu Linzhang Chen Yu Li [Abstract] established the sediment trace decabromodiphenyl oxide liquid dispersion of micro-extraction - floating Solvent Curing - High Performance Liquid Chromatography - UV method (DLLME-SFO-HPLC-UV. orthogonal test data as the training samples by BP (Back propagation neural network model optimized micro-dispersed liquid-liquid extraction - floating solvent curing conditions: 1.00 mL of methanol as a dispersing agent, extraction solvent is 35.0 μL dodecanol, NaCl concentration was 10.00%, extraction time 10 min and pH = 5, the extraction rate (ER up to 62.22%. The linear range of 3.5 ~ 1400 ng / g (r = 0.9960), limit of detection (LOD and limit of quantification (LOQ were 2.3 pg / g (S / N = 2 and 5.6 pg / g (S / N = 5, the actual sample recoveries were 97.7% ~ 104.2%. The method set extraction, enrichment and separation steps in one, simplifying the sediments Deca diphenyl ether pre-treatment process. [Keywords:] dispersed liquid-liquid microextraction; floating solvent curing; high performance liquid chromatography - UV method; sediments; decabromodiphenyl ether; multilayer feedforward neural networks Abstract A method for the determination of decabrominated diphenyl ether (decaBDE) in sediment samples at trace level using dispersive liquid-liquid microextraction based on the solidification of floating organic drop (DLLME-SFO) and high performance liquid chromatography-ultraviolet detector (HPLC-UV ) has developed.Based on the data of interactive orthogonal array design, the optimization experimental conditions were obtained with BP artificial neural network model: 1.00 mL methanol as dispersive solvent, 35.0 μL dodecanol as extractive solvent, 10.00% NaCl, pH 5, and extraction in 10 min.The extraction recovery (ER) was 62.22% at the extraction