湿法冶金渣中硫的化学回收-有色金属科学与工程.doc

文章编号： 湿法冶金渣中硫的化学回收 章青1,郭年祥1,谭秀珍1,胡娇2 (1. 江西理工大学冶金与化学工程学院, 江西省 赣州市 341000 2. 广东宝钢湛江钢铁有限公司, 广东省 湛江市 524000） 摘 要：我国是个硫磺用量大国，硫磺生产小国，硫磺是一种重要的化工产品和基本工业原料，为了节约资源以及提高资源的利用率，重新回收各种湿法冶金渣中的单质硫是有必要的. 硫的湿法回收方法有很多，主要为物理法和化学法，物理法回收硫对设备和物料有较高要求，具有一定的局限性，而化学法能处理各种物料，在一定程度上弥补了物理法的不足. 化学法除了常用的硫化铵法、二甲苯法、煤油法、四氯乙烯法外，还有硫化钠-二氧化硫法、新型脱硫剂法，比如四氢萘、苯乙烯、十氢萘和甲苯等，对于不溶性硫磺的回收方法也有一定新的进展.就化学法，介绍了各种化学法回收硫的原理及其优缺点. 关键词：湿法冶金；浸出渣；元素硫；化学法；回收 中图分类号： 文献标识码：A Chemical methods recycle sulfur of hydrometallurgical slag ZHANG Qing1, GUO Nian-xiang1, TAN Xiu-zhen1, HU Jiao2 (1.School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China; 2.Guang Dong Baosteel Zhan Jiang Iron and Steel Corporation, Guangdong 524000, China) Abstract: The usage of sulfur is very big in our country, but the output of sulfur is not high. Sulfur is an important chemical product and basic industrial material, in order to save resources and improve the utilization of recources, it becomes necessary to recy- 收稿日期： 作者简介:章青（1988- ）,女, 汉族, 硕士, 主要从事高硫渣脱硫提取有价金属研究, E–mail:zhangqing198693@126.com. cle sulfur of hydrometallurgical slag. Mainly hydrometallurgical methods of recycling sulfur are physical and chemical methods. Physical methods of recycling sulfur have a high requirement for equipments and materials, thus have a certain limitation. However, chemical methods can process various of materials and compensate for the lack of physical methods to a certain extent. In addition to common chemical methods, such as ammonium sulfide, xylene, kerosene, PCE, there are sodium sulfide-sulfur dioxid, new desulfurizer, like tetrahydronaphthalene, styrene, decahydronaphthalene, toluene and so on, insoluble sulfur recovery methods also have a new progress. The principles of chemical recovery of sulfur are different and have their own advantages and disadvantages. Key words: hydrometallurgy; leaching slag; sulfur; chemical way; recycle 1 前 言 很多金属都会和