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Marks the beginning of the chemical constituents of the umbrella.docVIP

Marks the beginning of the chemical constituents of the umbrella.doc

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    Marks the beginning of the chemical constituents of the umbrella

     PAGE \* MERGEFORMAT 4 Marks the beginning of the chemical constituents of the umbrella 2.2.2 Compound 2 light yellow powder (methanol), FeCl3 reaction was positive, ESI-MS m / z: 541 [M + Na] +, 356 [M-Glc] +, 1 H NMR (DMSO-d6, 400 MHz ) : 11.83 (1 H, s, 5-OH), 7.31 (2 H, d, J = 8.8 Hz, 2 ‘, 6’-H), 6.78 (2 H, d, J = 8.8 Hz, 3’ , 5’-H), 6.28 (1 H, s, 6-H), 5.82 (1 H, d, J = 6.0 Hz, OH), 5.30 (1 H, d, J = 4.8 Hz, OH), 5.12 (1 H, d, J = 4.4 Hz, OH), 5.08 (1 H, t, 2’’-H), 5.03 (1 H, d, J = 11.5 Hz, 2-H), 4.90 (1 H, d, J = 7.2 Hz, 1’’’-H), 4.58 (1 H, dd, J = 11.6 Hz, 5.6 Hz, 3-H), 4.62 (1 H, d, J = 5.2 Hz, 3-OH ), 3.69 (2 H, m, 6’’’-H), 3.43 (1 H, m, 5’’’-H), 3.28 (1 H, m, 4’’’-H), 3.24 (1 H, m, 3’’’-H), 3.14 (2 H, br d, J = 7.2 Hz, 1’’-H), 2.99 (1 H, m, 2’’’-H), 1.56 (3H , s, 5’’-H), 1.49 (3H, s, 4’’-H), 13 CNMR (DMSO-d6, 100 MHz) : 199.2 (4-C), 163.2 (7-C), 161.0 (8a-C), 158.7 (4’-C), 157.70 (5-C), 130.4 (1’-C), 129.3 (2 ‘, 6’-C), 127.7 (3’’-C), 122.4 (2’’-C), 114.9 (3 ‘, 5’-C), 109.0 (8-C), 101.9 (4a-C), 100.3 (1’’’-C), 95.4 (6-C), 82.9 (2-C), 77.2 (5’’’-C), 76.6 (3’’’-C), 73.3 (2’’’-C), 71.9 (3-C), 69.6 (4’’’ -C), 60.7 (6’’’-C), 25.6 (5’’-C), 21.4 (1’’-C), 17.6 (4’’-C). The above data with the literature [5] are basically the same Therefore, identification of compounds 2 Phellamurin. 2.2.3 Compound 3 light yellow needle crystal (acetone), mp 216 ~ 217 , ESI-MS m / z: 162 (M +), 134,105,78,1 H-NMR (DMSO-d6, 400 MHz) : 7.92 (1 H, d, J = 9.6 Hz, 3-H), 7.51 (1 H, d, J = 8.4 Hz, 5-H), 6.77 (1 H, dd, J = 8.8 Hz, 2.4 Hz, 6 - H), 6.70 (1 H, d, J = 1.6 Hz, 8-H), 6.18 (1 H, d, J = 9.6 Hz, 2-H), the above data with the literature [6] are basically the same, so identification of compounds 3 of 7 - hydroxy coumarin (umbelliferone). 2.2.4 Compound 4 light yellow powder (chloroform - methanol), FeCl3 reaction was positive, ESI-MS m / z: 168 (M +), 153,125,108,97,1 H-NMR (DMSO-d6, 400 MHz) : 12.45 (1 H, s,-COOH), 9.84 (1 H, s, 3-OH), 7.41 ~ 7.43 (2 H, m, 2, 6-H), 6.82

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