Aqueous Synthesis and Characterization of CdSeZnO Core-Shell Nanoparticles英文文献资料.docVIP

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Aqueous Synthesis and Characterization of CdSeZnO Core-Shell Nanoparticles英文文献资料.doc

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Aqueous Synthesis and Characterization of CdSeZnO Core-Shell Nanoparticles英文文献资料

HindawiPublishingCorporation JournalofNanomaterials Volume2011,ArticleID514205,6pages doi:10.1155/2011/514205 ResearchArticle AqueousSynthesisandCharacterizationofCdSe/ZnO Core-ShellNanoparticles B.P.Rakgalakane andM.J.Moloto 1 2 1 2 DepartmentofChemistry,VaalUniversityofTechnology,PrivateBagX021,Vanderbijlpark1900,SouthAfrica DepartmentofChemicalTechnology,UniversityofJohannesburg,P.O.Box17011,Doornfontein2028,SouthAfrica CorrespondenceshouldbeaddressedtoM.J.Moloto,makwenam@vut.ac.za Received24June2011;Accepted24August2011 AcademicEditor:AnukornPhuruangrat Copyright?2011B.P.RakgalakaneandM.J.Moloto. This is an open access article distributed under the Creative Commons AttributionLicense,whichpermitsunrestricteduse,distribution,andreproductioninanymedium,providedtheoriginalworkis properlycited. Core-shellnanomaterialsbasedonCdSeasthecoreandZnOastheshellwerepreparedusinganaqueousrouteinvolvingtheuseof CdsaltandNaBH4inreactionwithSetogenerateCdSeinthepresenceofthioglycerol(TG)asastabilizer.ZnOhasbeenprepared atpH12usingstrongerbasesuchasNaOHatlowerconcentrationandbyvaryingamountsofZn 2+ ionsrangingfrom2.5,5, 25mL,and50mLtopreparecore-shellnanomaterials.TheabsorptionandemissionspectralfeaturesaredominatedbyCdSe nanoparticleswithtypicalshiftintheemissionmaximared-shiftedinrelationtothebandedges.Thereisanobservablechangein thebandedgefromthecoreastheamountofZnOisincreased.TheTEMfeaturesshowedtheformationofthecore-shellfrom thevolumeof5mLwhichisindicatedbythethinlayerofshellonthesurfaceoftheCdSecore. 1.Introduction TheUV-VisabsorptionmaximumofCdSe/ZnOcore-shell materialshowedaminorredshiftfromthatofbareCdSe nanocrystalsandtherewasanincreased?uorescentintensity whenZnOnanomaterialpassivatedonthesurfaceCdSena- nocrystals. Core-shellnanocrystalsarenanostructurescomposedofat leasttwomaterialsinanonion-likestructurewiththesize rangeof20–200nm[1,2].Core-shellnanomaterialsbased on semiconductor cores coated by an oxide shell are very interesting especially