Aqueous Synthesis of CdTe Quantum Dot Using Dithiol-Functionalized Ionic Liquid英文文献资料.docVIP
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Aqueous Synthesis of CdTe Quantum Dot Using Dithiol-Functionalized Ionic Liquid英文文献资料
HindawiPublishingCorporation
JournalofNanomaterials
Volume2012,ArticleID519458,6pages
doi:10.1155/2012/519458
ResearchArticle
AqueousSynthesisofCdTeQuantumDotUsing
Dithiol-FunctionalizedIonicLiquid
SukYoungChoi, JongPilShim, DongSunKim, TaeYoungKim, andKwangS.Suh
1 1 1 2 1
1
2
DepartmentofMaterialsScienceandEngineering,KoreaUniversity,5-1Anam-dong,Seongbuk-gu,Seoul136-713,RepublicofKorea
ElectronicMaterialsandDeviceResearchCenter,KoreaElectronicsTechnologyInstitute,Gyeonggi-do463-816,RepublicofKorea
CorrespondenceshouldbeaddressedtoKwangS.Suh,suhkwang@korea.ac.kr
Received6August2011;Accepted28October2011
AcademicEditor:SomchaiThongtem
Copyright?2012SukYoungChoietal. This is an open access article distributed under the Creative Commons Attribution
License,whichpermitsunrestricteduse,distribution,andreproductioninanymedium,providedtheoriginalworkisproperly
cited.
We report on an aqueous synthesis of cadmium telluride (CdTe) nanocrystals by using dithiol-functionalized ionic liquids
(dTFILs).ThedTFILsweredesignedtohavedithiolandvinylimidazoliumfunctionalgroupsandusedasaligandmoleculeofCdTe
quantumdot(QD)toutilizethebidendatechelateinteractiona?ordedbythedithiolgroupsofdTFILs.Thephotoluminescence
quantumyieldofdTFIL-cappedCdTeQDsreachedupto~40%,andtheirluminescentpropertywasmaintainedfor8weeks,
suggestinganimprovedstabilityinwaterphase.ThisapproachwillprovideanewsyntheticroutetothewatersolubleQDs.
1.Introduction
Inthisregard,thedirectsynthesisofQDsinwaterphase
providesanattractivealternativebecauseofitssimplicityand
useofrelativelysoftcondition[25–27].Priorreportsshowed
that cadmium telluride (CdTe) QDs with moderately high
photoluminescencequantume?ciency(QE)havebeenpro-
duced via aqueous synthetic route with a thiol capping li-
gandssuchasmercaptocarbonicacid,2-aminoethanethiol,
anddihydrolipoicacid[28–30].However,theenvironmental
instabilityofQDspreparedbyaqueoussyntheticmethodwas
alsoreported.Ther
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