Biofunctional Characteristics of Lignite Fly Ash Modified by Humates A New Soil Conditioner英文文献资料.docVIP

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Biofunctional Characteristics of Lignite Fly Ash Modified by Humates A New Soil Conditioner英文文献资料.doc

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Biofunctional Characteristics of Lignite Fly Ash Modified by Humates A New Soil Conditioner英文文献资料

HindawiPublishingCorporation BioinorganicChemistryandApplications Volume2010,ArticleID457964,8pages doi:10.1155/2010/457964 ResearchArticle BiofunctionalCharacteristicsofLigniteFlyAshModi?edby Humates:ANewSoilConditioner KonstantinosChassapis, MariaRoulia, EvangeliaVrettou, DespinaFili, 1 1 1 2 andMonicaZervaki 2 1 2 InorganicChemistryLaboratory,DepartmentofChemistry,UniversityofAthens,Panepistimiopolis,15771Athens,Greece SchoolofChemicalEngineering,NationalTechnicalUniversityofAthens,9HeroonPolytechniou,ZografouCampus, 15773Athens,Greece CorrespondenceshouldbeaddressedtoKonstantinosChassapis,chassapis@chem.uoa.gr Received29December2009;Accepted2March2010 AcademicEditor:SpyrosPerlepes Copyright?2010KonstantinosChassapisetal.ThisisanopenaccessarticledistributedundertheCreativeCommonsAttribution License,whichpermitsunrestricteduse,distribution,andreproductioninanymedium,providedtheoriginalworkisproperly cited. Flyashsuper?ciallymodi?edwithhumicsubstancesfromtheMegalopolisligniticpowerplantwaspreparedandevaluatedfor agriculturaluses.UV-visspectrophotometryandIRspectroscopyrevealedthat?yashshowshighsorptione?ciencytowards humicsubstances.AdsorptionproceedsstepwiseviastrongCoulombicandhydrophophicforcesofattractionbetweenguestand hostmaterials.Langmuir,Freundlich,BET,Harkins-Jura,andDubinin-Radushkevichisothermmodelswereemployedtoevaluate the ongoing adsorption and shed light to the physicochemical properties of the sorbent-adsorbatesystem. Humic substances desorption and microbial cultivation experiments were also carried out to examine the regeneration of the humates under washingandexplorethepossibilityofthismaterialacclimatizinginrealsoilconditions,bothusefulforbiofunctionalagricultural applications. 1.Introduction chemicalpropertiesof?yashdependonthenatureofparent coal[5,6].Alltheseapplicationsarebasedonthepresenceof basicmineralelementsresemblingearth’scrust,whichmakes themexcellentsubstituentfornaturalmaterials. The