SO4 2-／ZrO2催化烷烃异构化反应的研究进展.pdfVIP

学兔兔 石 油 化 工 · 94· PETR0CHEMICAL TECHN0L0GY 2010年第39卷第1期 i进展与述评l 气忐 ／ sol一／ZrO2催化烷烃异构化反应的研究进展 汪颖军，刘成双，李小辉 (大庆石油学院 化学化工学院，黑龙江 大庆 163318) [摘要]概述了so；一／ZrO：固体超强酸催化剂的制备方法，详细介绍了浸渍液浓度、沉淀剂、焙烧温度、金属前体、形成沉淀时的 pH和陈化温度等制备条件对so；一／ZrO2催化剂活性的影响，综述了s0：一／ZrO2催化剂的改性方法及sol一／ZrO2催化剂催化烷 烃异构化反应的研究进展，并在此基础上对s0j一／ZrO 催化剂今后的研究发展方向进行了展望。 [关键词]固体超强酸催化剂；氧化锆；烷烃；异构化 [文章编号]1000—8144(2010)01—0094—07 [中图分类号]TQ 203．4 [文献标识码]A Reseach Progress of sol一／ZrO2 Catalyst in Alkanes Isomerization Wang Yingjgn，Liu Chengshuang，Li Xiaohui (College of Chemistry and Chemical Engineering，Daqing Petroleum Institute，Daqing Heilongjiang 163318，China) l Abstract J Owing to environmental restrictions on emissions，alkane isomerization will become an important measure for production of the clean gasoline．sO 一／ZrO2 solid super acid catalyst has advantages of high acid strength，easy preparation，heat—resistance，and SO on．It has high catalytic activity to alkane isomerization．In this paper，preparation methods of so24一／ZrO2 were reviewed ． Effects of preparation conditions including impregnation solution concentration，precipitant，calcination temperature，metallic precursor，precipitation pH and aging temperature on characteristic properties of the catalysts were summarized．Research progresses in alkane isomerization catalyzed by so24一／ZrO2 and modified SOl一／ZrO2 were reviewed．Based on these，the directions