Sr掺杂对CaMnO_（3＋δ）基化合物高温电学性能的影响.pdfVIP

学兔兔 化 工 进 展 201 1年第30卷第5期 CHEMICAL INDUSTRY AND ENGINEERING PROGRESS ·1065· Sr掺杂对CaMnO3+ 基化合物高温电学性能的影响 贾 坤，魏长平，许 洁，吕志军，于敏娜 (长春理工大学化学与环境工程学院，吉林 长春 130022) 摘 要：以硝酸盐为原料，采用溶胶一凝胶法结合常压烧结制备出CahSrxMnO3陶瓷块体材料，研究了其物相、 微观形貌以及sr掺杂对其高温电学性能的影响。结果表明，制备出的块体材料为单一物相，为正交晶系钙钛矿 结构，结构致密，sr掺杂可以有效改变其电学性能，sr取代Ca位的材料Seebeek系数变化不大但电阻率降低； 当Sr的掺杂量为0．1时可获得最佳的电学性能，600℃时它的功率因子为24．03x10 W／(m．K )。 关键词：溶胶一凝胶法；热电材料；掺杂：锰酸钙；电学性能 中图分类号：TN 3 文献标志码：A 文章编号：1000—6613(2011)05—1065—04 Effects of Sr doping on high temperature electric properties of CaMn03+ 一based compounds JIA Kun，WEIChangping，XUJie，LOZhQun，YUMinna (School of Chemistry and Environmental Engineering，Changchun University of Science and Technology Changchun 130022，Jilin，China) Abstract：Cal SrxMnO3(x=0，0．05，0．1)ceramic samples were prepared by using the sol—gel method and sintering in air with nitrales as starting materials．The phase composition，microstructure and electric properties of Sr doped samples were investigated．The results showed that the Cal SrxMn03 ceram ic samples was single phase and had condensed microstructure．Sr doped samples had better electric properties．The substitution of Sr for Ca had no significant effect on Seabeek coefficient but decreased its electrical resistivity，the highest power factor was 24．03x10～w／(m．K )at 600℃ for the sample of Cao 9Sr01Mn03． ． Key words：sol—gel method；thermoelectric materials；doping；CaMnO3；electric properties 热电材料又称温差电材料，是一种将热能和电 Lao． 9BiolNi