X-5大孔树脂对黄芪异黄酮的吸附特性.pdfVIP

学兔兔 化 工 进 展 2013年第32卷第1期 CHEMICAL INDUSTRY AND ENGINEERING PROGRESS ·65· X．5大孑L树脂对黄芪异黄酮的吸附特性 徐祖伟，于朝生，窦 烁 (东北林业大学理学院，阻燃材料分子设计与制备黑龙江省重点实验室，黑龙江 哈尔滨 150040) 摘 要：通过对比5种大孔树脂对黄芪异黄酮的吸附和解吸特性，发现X．5大孔树脂最适用于吸附黄芪异黄酮， 并进一步采用静态吸附法研究了X．5树脂对黄芪异黄酮的吸附动力学和热力学特性。动力学研究表明，准二级动 力学相对于其它模型而言能够更好地描述黄芪异黄酮的吸附过程，颗粒内扩散是整个吸附过程的主要速率控制 步骤；黄芪异黄酮的吸附符合Langmuir等温吸附模型。热力学研究表明，△G00即吸附是自发进行的， 和 △Js‘J分别为 8．021 kJ／mol和 62．51 J／(mol·K)说明x一5大孔树脂对黄芪异黄酮的吸附是以熵为主要驱动力的吸热 过程。 关键词：X．5大孔树脂；黄芪异黄酮；动力学；热力学 中图分类号：O 647．31；TQ 465．5 文献标志码：A 文章编号：1000—6613(2013)01—0065—08 DoI：10．3969~．issn．1000．6613．2013．01．Olo Adsorption characteristics of isoflavones from aqueous solutions by X-5 macroporous resin XUZuwei， Chaosheng，DOUShuo (Department ofChemistry，Northeast Forestry University，Heilongjiang Key Lab ofMolecular Design and Preparation ofFlame Retarded Materials，Harbin 150040，Heilongiiang，China) Abstract：Through comparing adsorption and desorption characteristics of milk vetch root(Astragalus) isoflavones on five types of macroporous resin．it was found that X一5 macroporous resin was the most suitable one for the adsorption of isoflavones．Static adsorption experiments were carried out to investigate the adsorption kinetics and thermodynamics．Kinetics study indicated that the adsorption process could be best described by the pseudo—second．order model。and was controlled mainly by intra．particle diffusion．The isothermal adsorption followed the Langmuir mode1．The thermodynamic properties，i．e．AG00，△ =8．021 kJ／mol and ASO=62．51J／(mol‘K)，revealed that the