Zr （4＋）合成梳型结构聚羧酸系高效减水剂.pdfVIP

学兔兔 化 工 进 展 ·5l6· CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 2010年第29卷第3期 用固体强酸催化剂so 一／Zr4+合成梳型结构聚羧酸系高效减水剂 黎朝晖，侯书恩，赵新颖，黄玉娟，王凤翔 (中国地质大学材料科学与化学工程学院，湖北 武汉 430074) 摘 要：采用固体强酸so4一／Zr4 作为催化剂合成中间体 PA，再用其制备具有梳型结构的聚羧酸系减水剂 PAMMA。结果表明，当催化剂添加量为聚己二醇质量的0．75％时，生成的PA酯化率为97．6％，且催化剂经过 回收后能重复使用；讨论了合成的减水剂分子及其应用于华新P42．5水泥时的流变性能、共混形态、抗折、抗压 等力学性能。采用so4一／zr4 作为催化剂合成的高性能减水剂，红外图谱表明该减水剂分子结构和瑞士sika公 司的Viscocrete 3000型高效减水剂有一定相似性，应用于水泥时，在0．5％的掺量下能达到315．5 mln的流动度， 同时能使后期强度提高约 125％。 关键词：固体强酸；梳型；聚羧酸系减水剂 中图分类号：TQ 316．343 文献标识码：A 文章编号：1000—6613(2010)03—0516—05 Synthesis of comb-like polycarboxylate based superplasticizer catalyzed by solid superacid S042-]Zr4+ LIZhaohui，HOUShu’en，ZHA0 Xinying，HUANG Yujuan，WANG Fengxiang (School ofMaterial ScienceChemical Engineering，China University ofGeosciences，Wuhan 430074，Hubei，China) Abstract：Poly—carboxylic acid water reducer agent MMA with comb—like structure was prepared from intermediate PA that was synthesized using solid superacid S0 一／Z as catalyst．The molecular structure and mechanical properties of the obtained Water reducer agent were investigated，such as rheological property，morphology of the blend，flexural and compressive resistance when applied in Huaxin P42．5 cement．Results showed that the Water reducer agent obtmned by using t11e present method have good perform ance，and its molecular structure is similar with that of Viscocrete 3000 of Sika Company．Application in cement proved that the obtmned water reducer agent Can significantly reduce water consumption，the 28D strength increase 125％as compared