ZrO-2合成甲醇催化剂的催化性能.pdfVIP

学兔兔 化 工 进 展 ·820· CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 20 1 3年第32卷第4期 稀土助剂Pr改性Cu／Zn／ZrO2合成甲醇催化剂的催化性能 覃志强，高文桂，王 华，韩 冲，郭 伟 (昆明理工大学冶金节能减排教育部工程研究中心，云南省复杂有色金属资源清洁利用国家重点实验室 (培育基地)，云南 昆明 650093) 摘 要：采用共沉淀法制备了Cu／ZrdZrO2催化剂，并以稀土元素镨 (Pr)为助剂添加不同含量对其进行改性。通 过XRD、H2-TPR、CO2一TPD等表征手段考察了稀土助剂Pr203的含量对Cu／Zn／ZrO2催化剂结构的影响。在固定 床连续流动反应装置上考察了5种助剂含量改性的Cu／ZrdZrO2催化利对CO2加氢合成甲醇反应的催化性能。结 果表明：加入稀土助剂后，催化剂的表面碱性明显增强，有效地促进了活性组分的分散，稳定了催化剂的活性 中心。当Pr203的含量为3％时，cu／ZrdZrO2催化剂催化活性最佳 关键词：稀土助剂；CO2加氢；氧化镨；合成甲醇 中图分类号：O 643 文献标志码：A 文章编号：1000—6613(2013)04—0820—04 DoI：10．3969~．issn．1000—6613．2013．04．016 Research on rare—earth promoter Pr-modified Cu／Zn／Zr02 catalyst for methanol synthesis QINZhiqiang，GAO Wengui，WANG Hua，HAN Chong，GUO Wei (Engineering Research Center ofMetallurgy Energy Conservation and Emission Reduction，Ministry ofEducation，State Key Laboratory Breeding Base of Complex Nonferrous Metal Resources Cleaning Utilization in Yunnan Province， Kunming University ofScience and Technology，Kunming 650093，Yunnan，China) Abstract：A series of Cu／Zn／ZrO2 catalysts were prepared by the CO．precipitation method and modified via the addition of different amounts of Pr as rare—earth promoter．The influence of Pr201 amount on the structure of Cu／Zn／ZrO2 catalyst was investigated by using XRD，H2-TPR and C02．TPD．The catalytic performances of C02 hydrogenation to methanol over Cu／Zn／Zr02 catalysts modified by five different amounts of Pr promoters were tested in a fixed—bed Plug flOW react