ZrO2催化果糖脱水合成5-羟甲基糠醛.pdfVIP

学兔兔 化 工 进 展 2014年第33卷第1期 CHEMICAL INDU~STRY AND ENGINEERING PRO q,GRESS ·105· 固体酸WO3／ZrO2催化果糖脱水合成5．羟甲基糠醛 刘彦丽，王福余，王崇，赵振波 (长春工业大学化学与生命科学学院，吉林 长春 130012) 摘要：用共沉淀．热回流处理法制备了系列WO3／ZrO2固体酸催化剂，通过调节w与Zr的摩尔比优化其对果糖脱 水制备5．羟甲基糠醛(5-HMF)的催化活性。利用X射线衍射(XRD)、N 吸脱附、氨气程序升温脱附(NI-I-~ ．TPD) 对材料的结构和酸性质进行了表征，并在以二甲基亚砜(DMSO)为溶剂、果糖为原料的催化体系中，考察催化 剂的用量、反应时间、反应温度等对5-HMF收率的影响。研究发现，热回流处理大大增加了样品的比表面积， 增强了样品的酸强度，当(w)： (zr)=0．I：I时，样品比表面积最大，催化活性最好，以其为催化剂，在130℃ 下反应3 h条件下，5-HMF收率最高可达80．29％。 关键词：WO；／Zr02；固体酸；果糖；5-羟甲基糠醛 中图分类号：TQ 032．4 文献标志码：A 文章编号：1000—6613(2014)01—0105—05 DoI．10．3969／j．issn．1000．6613．2014．01．018 WO3／ZrO2 for fructose dehydration to 5-hydroxymethylfurfural as a solid acid catalyst LIU Yanli。WANG Fuyu，WANG Chong，ZHA0 Zhenbo (School ofLife Sciences and Chemistry，Changchun University ofTechnology，Changchun 130012，Jilin，China) Abstract：Catalytic dehydration of fructose to 5-hydroxymethylfurfural r5．HMF)was studied and improved by synthesizing series of solid acid catalyst WO3／ZrO2 with different mole ratio of W tO Zr using CO—precipitation with hot reflux method．The structure and properties of the catalysts thus synthesized were investigated by X-ray diffraction(XRD)，N2 sorption，temperature—programmed desorption of(NH3：．TPD)，and then the jinfluence of temperature，mass ration of fructose／catalyst and reaction time on the yield of 5一HMF from fructose were studied jin dimethyl sulfoxide．These studies showed that specific surface area and acid strength of the catalysts were]increased greatly by hot reflux method，and an optimized 5一HMF yield of 80．29％was obtained with 3 h at 1 30 ℃ in the presence of the sample