Organic Extractives from Mentha spp. Honey and the Bee-Stomach Methyl Syringate, Vomifoliol, Terpenediol I, Hotrienol and Other Compounds 英文参考文献.docVIP
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Molecules 2010, 15, 2911-2924; doi:10.3390/moleculeOPEN ACCESS
molecules
ISSN 1420-3049
/journal/molecules
Article
Organic Extractives from Mentha spp. Honey and the
Bee-Stomach: Methyl Syringate, Vomifoliol, Terpenediol I,
Hotrienol and Other Compounds
Igor Jerkovi? 1,*, Gordana Hegi? 2, Zvonimir Marijanovi? 3 and Dragan Bubalo 2
1
Faculty of Chemistry and Technology, University of Split, N. Tesle 10/V, 21000 Split, Croatia
2
Faculty of Agriculture, University of Zagreb, Sveto?imunska 25, 10000 Zagreb, Croatia
3
Marko Maruli? Polytechnic in Knin, P. Kre?imira IV 30, 22300 Knin, Croatia
* Author to whom correspondence should be addressed; E-Mail: igor@ktf-split.hr.
Received: 22 March 2010; in revised form: 13 April 2010 / Accepted: 20 April 2010 /
Published: 22 April 2010
Abstract: The GC and GC/MS analyses of the solvent organic extractive from the stomach
of the bees, having collected Mentha spp. nectar, revealed the presence of methyl syringate
(6.6%), terpendiol I (5.0%) and vomifoliol (3.0%) that can be attributed to the plant origin.
Other major compounds from the bee-stomach were related to the composition of cuticular
waxes and less to pheromones. Organic extractives from Mentha spp. honey were obtained
by solvent-free headspace solid-phase microextraction (HS-SPME) and ultrasonic solvent
extraction (USE) and analyzed by GC and GC/MS. The major honey headspace
compounds were hotrienol (31.1%–38.5%), 2-methoxy-4-methylphenol (0.5–6.0%), cis-
and trans-linalool oxides (0.9–2.8%), linalool (1.0–3.1%) and neroloxide (0.9–1.9%).
Methyl syringate was the most abundant compound (38.3-56.2%) in the honey solvent
extractives followed by vomifoliol (7.0–26.6%). Comparison of the honey organic
extractives with the corresponding bee-stomach extractive indicated that methyl syringate
and vomofoliol were transferred to the honey while terpendiol I was partially transformed
to hotrienol
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