Solid-State Synthesis of Poly(3,4-dimethoxy-2,25,2- terthiophene) Comparison With Poly(terthiophene) and Poly(3,4-ethylenedioxy-2,25,2- terthiophene) 英文参考文献.docVIP

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Solid-State Synthesis of Poly(3,4-dimethoxy-2,25,2- terthiophene) Comparison With Poly(terthiophene) and Poly(3,4-ethylenedioxy-2,25,2- terthiophene) 英文参考文献.doc

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Solid-State Synthesis of Poly(3,4-dimethoxy-2,25,2- terthiophene) Comparison With Poly(terthiophene) and Poly(3,4-ethylenedioxy-2,25,2- terthiophene) 英文参考文献

Molecules 2012, 17, 8647-8660; doi:10.3390/moleculeOPEN ACCESS molecules ISSN 1420-3049 /journal/molecules Article Solid-State Synthesis of Poly(3,4-dimethoxy-2,2:5,2- terthiophene): Comparison With Poly(terthiophene) and Poly(3,4-ethylenedioxy-2,2:5,2- terthiophene) Tursun Abdiryim, Ruxangul Jamal, Aminam Ubul and Ismayil Nurulla * Key Laboratory of Petroleum and Gas Fine Chemicals, Educational Ministry of China, College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, China; E-Mails: tursunabdir@ (T.A.); jruxangul@ (R.J.); aminam520@ (A.U.) * Author to whom correspondence should be addressed; E-Mail: ismayilnu@; Tel./Fax: +86-0991-858-3575. Received: 18 May 2012; in revised form: 27 June 2012 / Accepted: 13 July 2012 / Published: 23 July 2012 Abstract: A new terthiophene monomer: 3,4-dimethoxy-2,2:5,2-terthiophene (TMT) was synthesized and characterized by 1H-NMR, 13C-NMR and FTIR. The solid-state oxidative polymerizations of TMT were performed in various ratios of oxidant (FeCl3) to monomer (TMT). The resulting polymers were characterized by 1H-NMR, FTIR, UV-vis-NIR, GPC, X-ray diffraction, CV, as well as TGA and conductivity measurements. The structure and properties of poly (TMT) were compared with those of polyterthiophene [poly(TT)] and poly (3,4-ethylenedioxy-2,2:5,2-terthiophene) [poly(TET)] prepared under the same polymerization conditions. After comparative analysis with poly(TT) and poly(TET), the effects of the dimethoxy substituent and FeCl3 on the structural and physicochemical properties of the poly(TMT)s were discussed in depth. The comparison suggested that the dimethoxy-substituted polymer did not display higher crystallinity, thermal stability, conductivity and electrochemical activity than ethylenedioxy substituted one. The results also showed that the effect of FeCl3 on poly(TMT) was similar that seen with the poly(